Abstract
Cyanine, merocyanine, and styryl dyes that are derivatives of halo-, alkyl-, alkylene-, and arylthieno[2,3-d]thiazoles and halo- and alkylindolo[3,2-d]thiazoles were synthesized. It is shown that both electron-donor and electron-acceptor substituents in the 5 and 5′ positions of the heteroresidues of thienothiazolocarbocyanines lead to a more uniform distribution of the electron density in their chromophore than in the unsubstituted dye and to a bathochromic shift of the absorption maximum. Methyl groups in the heteroresidues of indolothiazolocarbocyanines give rise to a small bathochromic effect.
Similar content being viewed by others
Literature Cited
V. G. Zhiryakov and P. I. Abramenko, Khim. Geterotsikl. Soedin., No. 3, 488 (1969).
V. G. Zhiryakov, N. I. Astrakhantseva, P. I. Abramenko, and I. I. Levkoev, Dokl. Akad. Nauk SSSR, 219, 870 (1974).
P. I. Abramenko and T. K. Ponomareva, Khim. Geterotsikl. Soedin., No. 12, 1606 (1972).
P. I. Abramenko and T. K. Ponomareva, Zh. Vses. Khim. Obshchestva, 28, 114 (1983).
F. M. Hamer, The Cyanine Dyes and Related Compounds, Interscience, New York-London (1964).
V. A. Kosobutskii, G. I. Kagan, V. K. Belyakov, and O. G. Tarakanov, Zh. Strukt. Khim., 12, 822 (1971).
P. I. Abramenko and V. A. Kosobutskii, Khim. Geterotsikl. Soedin., No. 5, 626 (1978).
P. I. Abramenko and V. A. Kosobutskii, Khim. Geterotsikl. Soedin., No. 9, 1202 (1979).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1278–1283, September, 1988.
Rights and permissions
About this article
Cite this article
Dzyubenko, V.G., Pinkin, L.D. & Abramenko, P.I. Synthesis and absorption spectra of polymethine dyes — Derivatives of substituted thieno- and indolothiazoles. Chem Heterocycl Compd 24, 1059–1065 (1988). https://doi.org/10.1007/BF00474056
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00474056