Chemistry of Heterocyclic Compounds

, Volume 28, Issue 2, pp 201–204 | Cite as

Mass spectrometry of macroheterocycles. 2. Characteristics of the fragmentation of azacrown ethers under electron impact

  • A. I. Gren'
  • O. S. Timofeev
  • A. V. Mazepa
Article
  • 35 Downloads

Abstract

The fragmentation of aza-crown and diaza-crown ethers under electron impact was studied. It is shown that for the former the primary pathways of fragmentation of the molecular ions involve the intracyclic migration of a hydrogen atom and the elimination of C2H3O and CH2OH particles. A characteristic feature of the diaza-crown ethers is the ejection of a divinylaminyl radical.

Keywords

Hydrogen Ether Migration Mass Spectrometry Organic Chemistry 

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Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • A. I. Gren'
    • 1
  • O. S. Timofeev
    • 1
  • A. V. Mazepa
    • 1
  1. 1.A. V. Bogat-skii Physicochemical InstituteUkrainian Academy of SciencesOdessa

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