Abstract
The oxidation of trans-syn-trans-N-amino-11,14-dicyanoperhydroacridine with manganese dioxide or bromine gives two stereoisomeric 11,12-dicyanoperhydrofluorenes and two stereoisomeric 2-cyano-1-(2-cyanocyclohexylmethyl)-1-cyclohexenes. The oxidation of trans-anti-cis-N-amino- 11,14-dicyanoperhydroacridines with manganese dioxide gives three other stereoisomers of 11,12-dicyanoperhydrofluorene.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 104–108, January, 1976.
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Gamov, V.K., Kaminskii, V.A. & Tilichenko, M.N. Oxidation of stereoisomeric N-amino-11,14-dicyanoperhydroacridines. Chem Heterocycl Compd 12, 95–99 (1976). https://doi.org/10.1007/BF00473922
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DOI: https://doi.org/10.1007/BF00473922