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Synthesis and study of spiro [(indane-1,3-dione)-2,3′-azir-1′-ines] and their cleavage products

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Spiro[(indane-1,3-dione)-2,3′ (2′-substituted 1′-azirines)] were obtained by intramolecular cyclization of 2-acylindane-1,3-dione oximes. Their structures and properties were investigated, and it was established that the C-N and C-C single bonds are cleaved during opening of the three-membered ring.

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Literature cited

  1. L. S. Geita, I. É. Dalberg, and A. K. Grinvalde, Izv. Akad. Nauk LatvSSR, Ser. Khim., 494 (1974).

  2. T. Nishiwaki, T. Kitamura, and A. Nakano, Tetrahedron, 26, 453 (1970).

    Google Scholar 

  3. L. Geita and G. Vanag, Bul. Inst. Politehnic Iasi, 9, 171 (1963).

    Google Scholar 

  4. V. M. Berestovitskaya, A. S. Sopova, and V. V. Perekalin, Zh. Organ. Khim., 3, 1703 (1967).

    Google Scholar 

  5. G. Gregory, R. Moodie, and K. Schofield, J. Chem. Soc., B, 338 (1970).

    Google Scholar 

  6. P. W. Neber and G. Huh, Ann., 515, 283 (1935).

    Google Scholar 

  7. A. Hassner and F. Fowler, J. Am. Chem. Soc., 90, 2869 (1968).

    Google Scholar 

  8. T. Nishiwaki and T. Saito, J. Chem. Soc., C, 3021 (1971).

    Google Scholar 

  9. V. N. Zelmen, G. Ya. Vanag, and I. A. Stunda, Izv. Akad. Nauk LatvSSR, No. 1, 107 (1958).

    Google Scholar 

  10. L. S. Geita, I. É. Dalberga, and A. K. Grinvalde, Izv. Akad. Nauk LatvSSR, Ser. Khim., 114 (1973).

  11. L. S. Geita, I. É. Dalberga, and A. K. Grinvalde, Zh. Organ. Khim., 11, 803 (1975).

    Google Scholar 

  12. I. B. Mazheika, I. S. Yankovska, S. D. Sokolov, and I. N. Yudintseva, Khim. Geterotsikl. Soedin., 460 (1972).

  13. V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov, Dipole Moments in Organic Chemistry [in Russian], Khimiya, Leningrad (1968), p. 77.

    Google Scholar 

  14. Handbook of Dipole Moments [in Russian], Moscow (1971).

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, Riga

    L. S. Geita, L. É. Dalberga, A. K. Grinvalde & I. S. Yankovska

Authors
  1. L. S. Geita
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  2. L. É. Dalberga
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  3. A. K. Grinvalde
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  4. I. S. Yankovska
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 65–69, January, 1976.

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Geita, L.S., Dalberga, L.É., Grinvalde, A.K. et al. Synthesis and study of spiro [(indane-1,3-dione)-2,3′-azir-1′-ines] and their cleavage products. Chem Heterocycl Compd 12, 60–64 (1976). https://doi.org/10.1007/BF00473915

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  • DOI: https://doi.org/10.1007/BF00473915

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