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Researches on reactions of alpha oxides of cyclic olefins

I. reactions of 1-vinylcyclohexene — 3 dioxide with alpha chloroethers, dialkylphosphorous chloroanhydrides, and amines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reactions of 1-vinylcyclohexene — 3 dioxide with chloroethers (chlorodimethyl ether, chloromethylethyl ether, chloromethylpropyl ether) in the presence of zinc chloride, with diethyl and dipropylphosphorous chloroanhydrides, and with propylamine, butylamine and ethanolamine are described. IR absorption spectra show that the chloroethers and dialkylphosphorous chloroanhydrides add to 1-vinylcyclohexene-3 dioxide with opening of the oxide ring at the 6-carbon ring, while the amines add at the oxide ring across the exocyclic double bond.

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Authors and Affiliations

  1. Institute of Organic Chemistry As USSR, Kazan

    L. A. Mukhamedova, T. M. Malyshko & R. R. Shagidullin

Authors
  1. L. A. Mukhamedova
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  2. T. M. Malyshko
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  3. R. R. Shagidullin
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Mukhamedova, L.A., Malyshko, T.M. & Shagidullin, R.R. Researches on reactions of alpha oxides of cyclic olefins. Chem Heterocycl Compd 1, 320–324 (1966). https://doi.org/10.1007/BF00473800

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  • DOI: https://doi.org/10.1007/BF00473800

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