Chemistry of Heterocyclic Compounds

, Volume 22, Issue 10, pp 1126–1131 | Cite as

Heterocyclic analogs of pleiadiene. 59. Reaction of 1-acetonyl- and 1-phenacylperimidinium salts with hydrazine and ammonium acetate

  • V. V. Dal'nikovskaya
  • T. A. Kuz'menko
  • A. F. Pozharskii


1-Acetonyl-3-methyl- and 1-methyl-3-phenacylperimidinium salts react with hydrazine hydrate to give tetrahydro-derivatives of the hitherto unknown heterocyclic system 1,2,4-triazino[4,3-a]perimidine. On boiling in acetic acid with ammonium acetate, 3-phenacyl- and 3-(2′,4′-dimethyl)phenacyl-1-methylperidinium salts are converted into 1-methylamino-8-(4-phenylimidazol-1-y1)naphthalenes, with small amounts of 11-methylimidazo[1,2-a]perimidines also being formed.


Acetate Ammonium Hydrate Acetic Acid Organic Chemistry 
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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. V. Dal'nikovskaya
    • 1
    • 2
  • T. A. Kuz'menko
    • 1
    • 2
  • A. F. Pozharskii
    • 1
    • 2
  1. 1.M. A. Suslov Rostov State UniversityRostov-on-Don
  2. 2.Research Institute for Physical and Organic ChemistryRostov-on-Don

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