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Chemistry of Heterocyclic Compounds

, Volume 22, Issue 10, pp 1126–1131 | Cite as

Heterocyclic analogs of pleiadiene. 59. Reaction of 1-acetonyl- and 1-phenacylperimidinium salts with hydrazine and ammonium acetate

  • V. V. Dal'nikovskaya
  • T. A. Kuz'menko
  • A. F. Pozharskii
Article
  • 30 Downloads

Abstract

1-Acetonyl-3-methyl- and 1-methyl-3-phenacylperimidinium salts react with hydrazine hydrate to give tetrahydro-derivatives of the hitherto unknown heterocyclic system 1,2,4-triazino[4,3-a]perimidine. On boiling in acetic acid with ammonium acetate, 3-phenacyl- and 3-(2′,4′-dimethyl)phenacyl-1-methylperidinium salts are converted into 1-methylamino-8-(4-phenylimidazol-1-y1)naphthalenes, with small amounts of 11-methylimidazo[1,2-a]perimidines also being formed.

Keywords

Acetate Ammonium Hydrate Acetic Acid Organic Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. V. Dal'nikovskaya
    • 1
    • 2
  • T. A. Kuz'menko
    • 1
    • 2
  • A. F. Pozharskii
    • 1
    • 2
  1. 1.M. A. Suslov Rostov State UniversityRostov-on-Don
  2. 2.Research Institute for Physical and Organic ChemistryRostov-on-Don

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