Abstract
The UV spectra of a number of 3(5)-nitro-1,2,4-triazoles at 220–350 nm were studied. A dependence of the position of the K band in the spectra of 3-nitro-5-R-triazoles on the nature of the substituent (R) is shown, and transfer of the effect of direct polar conjugation through the triazole ring was detected. Correlation dependences between the frequency and σ +n (σ +n -σ 0) constants were found in the series of 1-methyl-3-nitro-5-R-triazoles.
Similar content being viewed by others
Literature cited
L. I. Bagal, M. S. Pevzner, V. Ya. Samarenko, and A. P. Egorov, Khim. Geterotsikl. Soedin., 1701 (1970).
E. G. Kovalev, Master's Dissertation, “Comparative study of the effect of N-arylation in the 1,2,4-triazole series” [in Russian], Sverdlovsk (1970).
M. R. Atkinson, E. A. Parkes, and J. B. Polya, J. Chem. Soc., 4256 (1954).
G. I. Chipen and V. Ya. Grinshtein, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 411 (1962).
S. F. Mason and A. R. Katritzky (editor), in: Physical Methods in Heterocyclic Chemistry, Academic Press (1963).
L. I. Bagal and M. S. Pevzner, Khim. Geterotsikl. Soedin., 558 (1970).
A. B. Tomchin and L. S. Éfros, Reakts. Sposobnost' Organ. Soed., 1, No. 2, 59 (1964).
V. A. Palm, Foundations of the Quantitative Theory of Organic Reactions [in Russian], Khimiya (1967), p. 191.
L. I. Bagal, M. S. Pevzner, A. I. Frolov, and N. I. Sheludyakova, Khim. Geterotsikl. Soedin., 259 (1970).
L. I. Bagal, M. S. Pevzner, N. I. Sheludyakova, and V. M. Kerusov, Khim. Geterotsikl. Soedin., 265 (1970).
L. I. Bagal, M. S. Pevzner, and V. Ya. Samarenko, Khim. Geterotsikl. Soedin., 269 (1970).
L. I. Bagal, M. S. Pevzner, A. P. Egorov, and V. Ya. Samarenko, Khim. Geterotsikl. Soedin., 702 (1970).
L. I. Bagal, M. S. Pevzner, A. P. Egorov, and V. Ya. Samarenko, Khim. Geterotsikl. Soedin., 997 (1970).
Author information
Authors and Affiliations
Additional information
See [1] for communication VIL
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 272–274, February, 1971.
Rights and permissions
About this article
Cite this article
Bagal, L.I., Pevzner, M.S. Heterocyclic nitro compounds. Chem Heterocycl Compd 7, 249–251 (1971). https://doi.org/10.1007/BF00473100
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00473100