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Furan acetal compounds

I. Study of the kinetics of hydrolysis of some substituted furan 1,3-dioxanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It is shown that furan 1,3-dioxanes are considerably more stable than analogous systems with acyclic structures in hydrolysis reactions. The process is described by a first-order kinetic equation and is a reversible monomolecular reaction. A correlation was observed between the rate constants for the hydrolysis of α′-substituted furan acetals and the magnitude of the solvatochromic effect and the Brown σ+ constants.

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Literature cited

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Authors and Affiliations

  1. Krasnodarsk Polytechnic Institute, USSR

    Z. I. Zelikman, A. L. Chekhun, V. L. Pogrebnaya & V. G. Kul'nevich

Authors
  1. Z. I. Zelikman
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  2. A. L. Chekhun
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  3. V. L. Pogrebnaya
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  4. V. G. Kul'nevich
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 152–155, February, 1971.

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Zelikman, Z.I., Chekhun, A.L., Pogrebnaya, V.L. et al. Furan acetal compounds. Chem Heterocycl Compd 7, 141–143 (1971). https://doi.org/10.1007/BF00473069

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  • DOI: https://doi.org/10.1007/BF00473069

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