Chemistry of Heterocyclic Compounds

, Volume 25, Issue 1, pp 63–66 | Cite as

Complexes of zirconium and hafnium with substituted phthalocyanines

  • Yu. M. Osipov
  • G. P. Shaposhnikov
  • V. P. Kulinich
  • R. P. Smirnov


The syntheses and electronic spectra of complexes of zirconium and hafnium with halo-, tert-butyl-, nitro-, and amino-substituted phthalocyanines are described. The nature and location of the substituents are shown to affect the electronic absorption spectra. The changes in the spectra of the synthesized complexes on going from DMF to H2SO4 solution are analyzed.


Zirconium Organic Chemistry Absorption Spectrum H2SO4 Electronic Absorption 
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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • Yu. M. Osipov
    • 1
    • 2
  • G. P. Shaposhnikov
    • 1
    • 2
  • V. P. Kulinich
    • 1
    • 2
  • R. P. Smirnov
    • 1
    • 2
  1. 1.Ivanovo Chemical Technological InstituteIvanovo
  2. 2.Institute for the Chemistry of Nonaqueous SolutionsAcademy of Sciences of the USSRIvanovo

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