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Heteroadamantanes and their derivatives. 14. Synthesis of 3,6-diazahomoadamantan-9-ols and their acetates

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Abstract

The reduction of 3,6-diazahomoadamantan-9-ones with metal hydrides gave 3,6-diazahomoadamantan-9-ols, which were convened to acetates by the action of acetic anhydride. The effect of the substituents in the nodal positions on the rates of reduction and acylation is demonstrated.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, 119435, Moscow

    A. I. Kuznetsov, I. A. Vladimirova, T. M. Serova & A. S. Moskovkin

Authors
  1. A. I. Kuznetsov
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  2. I. A. Vladimirova
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  3. T. M. Serova
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  4. A. S. Moskovkin
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Additional information

See [1] for Communication 13.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 804–809, June, 1991.

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Kuznetsov, A.I., Vladimirova, I.A., Serova, T.M. et al. Heteroadamantanes and their derivatives. 14. Synthesis of 3,6-diazahomoadamantan-9-ols and their acetates. Chem Heterocycl Compd 27, 631–635 (1991). https://doi.org/10.1007/BF00472514

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  • DOI: https://doi.org/10.1007/BF00472514

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