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Chemistry of Heterocyclic Compounds

, Volume 26, Issue 9, pp 1033–1038 | Cite as

Sigma-complexes in the pyrimidine series.

9. Alkylation of acetonyl anionic sigma-complexes of 5-nitropyrimidine
  • G. Ya. Remennikov
  • S. G. Vishnevskii
  • V. V. Pirozhenko
  • V. M. Cherkasov
Article
  • 29 Downloads

Abstract

The alkylation of acetonyl, anionic sigma-complexes of the 5-nitropyrimidine series with geminal substitution in the 2 or 6 position is studied. Depending on the position of the geminal substitution, the C(5) or the N(1) atom is alkylated to form 2,5- or 1,6-dihydropyrimidine, respectively.

Keywords

Organic Chemistry Pyrimidine Alkylation Acetonyl Pyrimidine Series 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • G. Ya. Remennikov
    • 1
  • S. G. Vishnevskii
    • 1
  • V. V. Pirozhenko
    • 1
  • V. M. Cherkasov
    • 1
  1. 1.Institute of Bioorganic ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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