Skip to main content
Log in

Synthesis and tranformations of trinitroethyl esters of pyrazoline-carboxylic acids

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Trinitroethyl esters of pyrazolinecarboxylic acids were synthesized by the reaction of trinitroethyl sters of unsaturated carboxylic acids with diazomethane. The reaction is stereospecific. The trinitroethyl esters of pyrazolecarboxylic acids and N-acyl derivatives of pyrazolines were isolated during a study of the chemical properties of the compounds obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. L. Fridman and G. S. Ismagilova, Zh. Organ. Khim., 7, 2437 (1971).

    Google Scholar 

  2. T. Jacobs, in: Heterocyclic Compounds [Russian translation], Vol. 5, Inostr. Lit., Moscow (1961), p. 42.

    Google Scholar 

  3. B. Eistert, M. Regitz, G. Heck, and H. Schwall, in: Methoden der Organischen Chemie, Vol. 10/4, Stuttgart (1968).

  4. A. L. Fridman, F. A. Gabitov, and A. D. Nikolaeva, Zh. Organ. Khim., 7, 1309 (1971).

    Google Scholar 

  5. K. Auwers and E. Cauer, Ann., 470, 284 (1929).

    Google Scholar 

  6. F. A. Gabitov and A. L. Fridman, USSR Author's Certificate No.230, 167 (1967); Byull. Izobr., No. 34, 31 (1968).

  7. B. V. Ioffe and D. D. Tsitovich, Khim. Geterotsikl. Soedin., 559 (1965).

  8. A. Ledwith and D. Parry, J. Chem. Soc., C, 1408 (1966).

    Google Scholar 

  9. J. Atherton and R. Fields, J. Chem. Soc., C, 1507 (1968).

    Google Scholar 

  10. W. Parham, F. Blake, and D. Theissen, J. Org. Chem., 27, 2415 (1962).

    Google Scholar 

  11. J. Tabushi, K. Takagi, M. Okano, and R. Oda, Tetrahedron, 23, 2621 (1967).

    Google Scholar 

  12. H. Paul and A. Kausmann, Ber., 101, 3700 (1968).

    Google Scholar 

  13. S. Andrews, A. Day, and A. McDonald, J. Chem. Soc., C, 787 (1969).

    Google Scholar 

  14. D. C. Ayres, Carbanions in Synthesis, American Elsevier (1966).

  15. M. Hill, US Patent No. 3,230,247 (1966); Ref. Zh. Khim., 23N713 (1967).

  16. R. Saunders, US Patent No., 2,994,714; Ref. Zh. Khim., 21L235 (1962).

Download references

Authors

Additional information

Communication VIII of the series “Reactions of Aliphatic Diazo Compounds.” See [1] for communication VII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 234–237, February, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gabitov, F.A., Fridman, A.L. & Nikolaeva, A.D. Synthesis and tranformations of trinitroethyl esters of pyrazoline-carboxylic acids. Chem Heterocycl Compd 8, 210–213 (1972). https://doi.org/10.1007/BF00472361

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00472361

Keywords

Navigation