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Reaction of 1,5-dikitones

VII. Aminomethylation of 1,3-diphenyl-1-(α,α-dimethyltetrahydro-γ-pyron-β′-yl)-3-Propanone

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1,3-Diphenyl-1-(α,α-dimethyltetrahydro-γ-pyron-β′-yl)-2-dimethylaminomethyl-3-propanone was obtained by Mannich condensation of 1,3-diphenyl-1-(α,α-dimethyltetrahydro-γ-pyronα′-yl)-3-propanone with formaldehyde and dimethylamine hydrochloride. Its deaminomethylation, deamination, and conversion to the corresponding oxatetrahydroquinoline on reaction with hydroxylamine hydrochloride were studied.

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Literature cited

  1. A. N. Saverchenko, V. A. Kaminskii, and M. N. Tilichenko, Khim. Geterotsikl. Soedin., 384 (1973).

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Authors and Affiliations

  1. Far-Eastern State University, Vladivostok

    A. D. Chumak, G. V. Pavel & M. N. Tilichenko

Authors
  1. A. D. Chumak
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  2. G. V. Pavel
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  3. M. N. Tilichenko
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Additional information

See [1] for communication VII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 738–740, June, 1973.

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Chumak, A.D., Pavel, G.V. & Tilichenko, M.N. Reaction of 1,5-dikitones. Chem Heterocycl Compd 9, 676–678 (1973). https://doi.org/10.1007/BF00472304

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  • DOI: https://doi.org/10.1007/BF00472304

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