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Chemistry of Heterocyclic Compounds

, Volume 23, Issue 12, pp 1284–1287 | Cite as

Synthesis of alkyl and alkenyl furyl sulfoxides and their behavior in the pummerer reaction

  • V. V. Litvinova
  • N. V. Fedorov
  • A. V. Anisimov
  • E. A. Viktorova
Article

Abstract

Oxidation of alkyl(alkenyl) furyl sulfides by hydrogen peroxide in glacial acetic acid affords alkyl(alkenyl) furyl sulfoxides, which react with acetic acid, acetic anhydride, and a mixture of acetic and trifluoroacetic anhydrides to give α-acyloxy-substituted and unsaturated sulfides as products, while for allyl 2-(5-methylfuryl) sulfoxide a thienofuran compound is obtained.

Keywords

Oxidation Hydrogen Acetic Hydrogen Peroxide Sulfide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • V. V. Litvinova
    • 1
  • N. V. Fedorov
    • 1
  • A. V. Anisimov
    • 1
  • E. A. Viktorova
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityMoscow

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