Abstract
A simple method is proposed for the measurement of the absorption spectra in the visible and UV regions of photocolored solutions of spiropyrans, formed by the action of constant lowintensity UV irradiation, and for the construction, on the basis of these data, of the absorption spectra of the merocyanine forms of spiropyrans. The absorption spectra of the merocyanine forms of two spiropyrans in various solvents are examined.
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G. I. Lashkov, M. V. Savost'yanova, A. V. Shablya, and T. A. Shakhverdov, in: Molecular Photonics [in Russian], Nauka, Leningrad (1970), p. 299.
J. C. Besnard, Theses l'Universite de Strasbourg (1966).
O. Shaudé, Cahieres de Physique, 8, 50–52 (1954).
M. B. Gordin and M. A. Gal'bershtam, Khim. Geterotsikl. Soedin., 425 (1971).
J. Hirshberg, R. Heiligman-Rim, and E. Fischer, J. Chem. Soc., 156 (1961).
E. Fischer, J. Phys. Chem., 71, 3704 (1967).
J. C. Metras, M. Mosse, and C. Wippler, J. Chim. Phys., 62, 659 (1965).
T. A. Shakhverdov, Teor. iÉksperim. Khim., 4, 421 (1968).
R. Heiligman-Rim, J. Hirshberg, and E. Fischer, J. Phys. Chem., 66, 2465, 2470 (1962).
A. I. Nogaideli, K. G. Dzhaparidze, M. I. Brodzeli, L. V. Devadze, D. P, Maisuradze, É. L. Kertsman, and M. Ya. Chubabriya, Coobshcheniya Akad. Nauk Gruz.SSR, 40, 607 (1965).
E. Berman, R. E. Fox, and F. D. Thomson, J. Am. Chem. Soc., 81, 5605 (1959).
G. I. Lashkov and A. V. Shablya, Optika i Spektroskopiya, 19, 821 (1965).
J. B. Flannery, J. Am. Chem. Soc., 90, 5660 (1968).
M. B. Gordin and M. A. Gal'bershtam, Khim. Geterotsikl. Soedin., 1159 (1971).
M. B. Gordin and M. A. Gal'bershtam, Kinetika i Kataliz, 12, 774 (1971).
K. B. Yatsimirskii, Spectroscopic Methods in the Chemistry of Complexes [in Russian], Khimiya, Moscow-Leningrad (1964), p. 6.
G. Derflinger and H. Lischka, Monatsh., 99, 1851 (1968).
L. G. S. Brooker, G. H. Keyes, R. H. Sprague, R. H. Van Dyke, E. Van Lare, G. Van Zandt, F. L. White, H. W. J. Cressman, and S. G. Dent, J. Am. Chem. Soc., 73, 5332 (1951).
L. G. S. Brooker, G. H. Keyes, and D. W. Heseltine, J. Am. Chem. Soc., 73, 5350 (1951).
A. I. Kiprianov, Usp. Khim., 29, 1336 (1960).
I. M. Kogan, Chemistry of Dyes [in Russian], Moscow (1956), p. 395.
J. H. Mathews, J. Am. Chem. Soc., 48, 562 (1926).
A. Rieche, Z. Angew. Chem., 44, 896 (1931).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1534–1538, November, 1972.
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Gal'bershtam, M.A., Mikheeva, L.M. & Samoilova, N.P. Electronic absorption spectra of merocyanine forms of spiropyrans. Chem Heterocycl Compd 8, 1386–1389 (1972). https://doi.org/10.1007/BF00471878
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DOI: https://doi.org/10.1007/BF00471878