Chemistry of Heterocyclic Compounds

, Volume 8, Issue 12, pp 1449–1450 | Cite as

Establishment of the configuration of 4-benzamido-3-oxo-2-(α-hydroxyamino-δ-carbomethoxybutyl)-thiophane

  • S. D. Mikhno
  • T. M. Filippova
  • T. N. Polyanskaya
  • N. S. Kulachkina
  • V. M. Berezovskii
Article
  • 22 Downloads

Abstract

Proton magnetic resonance spectroscopy was used to establish that the addition of hydroxylamine to the exocyclic double bond of 4-benzamido-3-oxo-2-(δ-carbomethoxybutylidene)-thiophane occurs stereospecifically; the compound formed has the trans configuration with respect to the substituents in the 2 and 4 positions.

Keywords

Spectroscopy Organic Chemistry Proton Magnetic Resonance Double Bond Thiophane 

Literature cited

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    S. D. Mikhno, T. M. Filippova, N. S. Kulachkina, T. N. Polyanskaya, I. M. Kustanovich, and V. M. Berezovskii, Khim. Geterotsikl. Soedin., 897 (1972).Google Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1974

Authors and Affiliations

  • S. D. Mikhno
    • 1
  • T. M. Filippova
    • 1
  • T. N. Polyanskaya
    • 1
  • N. S. Kulachkina
    • 1
  • V. M. Berezovskii
    • 1
  1. 1.All-Union Scientific-Research Vitamin InstituteMoscow

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