Chemistry of Heterocyclic Compounds

, Volume 27, Issue 11, pp 1173–1176 | Cite as

Diazocarbonyl derivatives of heterocycles. 7. Diazoacetyloxiranes from the interaction of haloalkyldiazoketones with arylaldehydes

  • V. G. Kartsev
  • Z. G. Aliev
  • T. S. Pokidova
  • L. O. Atovmyan


By the interaction of substituted benzaldehydes or pyridylaldehydes with 3-bromo-1-diazopropanone, a number of 1-aryl- and 1-pyridyl-2-diazoacetyloxiranes have been obtained. The IR, UV, and PMR spectra of these compounds are reported here, along with data from x-ray structure analysis.


Organic Chemistry Structure Analysis Benzaldehyde 
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Literature Cited

  1. 1.
    S. S. Chapyshev and V. G. Kartsev, Khim. Geterotsikl. Soedin., No. 7, 959 (1987).Google Scholar
  2. 2.
    N. F. Wolsey and D. D. Hammargren, Tetrahedron Lett., No. 24, 2087 (1970).Google Scholar
  3. 3.
    N. F. Wolsey and M. H. Khalil, J. Org. Chem., 38, 4216 (1973).Google Scholar
  4. 4.
    N. F. Wolsey and M. H. Khalil, J. Org. Chem., 40, 3521 (1975).Google Scholar
  5. 5.
    H. E. Zimmerman and L. Ahramjian, J. Am. Chem. Soc., 82, 5459 (1960).Google Scholar
  6. 6.
    L. Thijs, F. L. Smeet, P. J. M. Cillissen, J. Harmsen, and B. Svanenburg, Tetrahedron, 36, 2141 (1980).Google Scholar
  7. 7.
    A. Zhunke, Nuclear Magnetic Resonance in Organic Chemistry [Russian translation], Mir, Moscow (1974), p. 82.Google Scholar
  8. 8.
    A. N. Chekhlov, Kristallografiya, 26, 596 (1981).Google Scholar
  9. 9.
    Z. G. Aliev, L. O. Atovmyan, and V. G. Kartsev, Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2023 (1985).Google Scholar
  10. 10.
    Z. G. Aliev, V. G. Kartsev, L. O. Atovmyan, and G. N. Bogdanov, Khim.-farm. Zh., No. 8, 84 (1980).Google Scholar
  11. 11.
    Z. G. Aliev, A. M. Sipyagin, V. G. Kartsev, and L. O. Atovmyan, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 134 (1986).Google Scholar
  12. 12.
    V. I. Andrianov, Z. Sh. Safina, and B. L. Tarnopol'skii, Programs “Rentgen-75” [in Russian], OIKhF, Chernogolovka (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • V. G. Kartsev
    • 1
  • Z. G. Aliev
    • 1
  • T. S. Pokidova
    • 1
  • L. O. Atovmyan
    • 1
  1. 1.N. N. Semenov Institute of Chemical Physics, Chernogolovka BranchRussian Academy of SciencesUSSR

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