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3-Bromopyrylium salts

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Three new methods have been proposed for the synthesis of 3-bromopyrylium salts. An unsaturated 1,5-diketone is converted into a 3-bromopyrylium salt by allyl bromination and the addition of bromine to the double bond. 3-Bromopyrone, obtained by the bromination of dibenzoylacetone is converted by treatment with Grignard reagents into 3-bromopyrylium salts. Similar compounds have also been synthesized by the pyrylation of aromatic and heterocyclic compounds with 3-bromo-4-chloropyrylium salts obtained from 3-bromopyrone.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 873–877, July, 1973.

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Krivun, S.V., Sayapina, S.V. & Baranov, S.N. 3-Bromopyrylium salts. Chem Heterocycl Compd 9, 805–808 (1973). https://doi.org/10.1007/BF00471553

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  • DOI: https://doi.org/10.1007/BF00471553

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