Skip to main content
Log in

Structures of the products of formylation of 1,3,5-triphenyl- and 1,5 -diphenyl-3-stryl-2-pyrazolines

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It was established by means of IR and PMR spectra and chemical transformations that the products of the Vilsmeier formylation of 1,3,5-triphenyl- and 1,5-diphenyl-3-styryl-2-pyrazolines are the corresponding 1-(p-formylphenyl)-2-pyrazolines. The frequencies of the stretching vibrations of the carbonyl group and the chemical shift of the aldehyde proton of these compounds indicate considerable conjugation of the p electrons of the N1 atom of the pyrazoline ring with the aldehyde group.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. E. E. Baroni and K. A. Kovyrzina, Zh. Obshch. Khim., 33, 959 (1963).

    Google Scholar 

  2. S. V. Tsukerman, E. G. Buryakovskaya, Yu. S. Rozum, and V. F. Lavrushin, Zh. Prirodn. Soedin., 8, 453 (1968).

    Google Scholar 

  3. L. Bellamy, Infrared Spectra of Complex Molecules, Methuen (1958).

  4. V. G. Tishchenko, Master's Dissertation, Khar'kov (1967).

  5. A. Z. Karimova, V. G. Bocharov, K. A. Bochenkova, and P. I. Petrovich, Zh. Prirodn. Soedin., 11, 848 (1969).

    Google Scholar 

  6. A. Hassner and M. J. Michelson, J. Org. Chem., 27, 3974 (1962).

    Google Scholar 

  7. W. S. Brey and C. M. Valencia, Can. J. Chem., 46, 810 (1968).

    Google Scholar 

  8. J. S. Clovis, A. Eckell, R. Huisgen, R. Sustmann, G. Wallbillich, and V. Webemdörfer, Ber., 100, 1593 (1967).

    Google Scholar 

  9. R. Bartoshevich, V. Mechnikovska-Stolyarchik, and B. Opshondek, Methods for the Reduction of Organic Compounds [Russian translation], Inostr. Lit., Moscow (1960), Chap. 6.

  10. E. E. Baroni, K. A. Kovyrzina, and E. A. Andreeshchev, Zh. Obshch. Khim., 30, 2002 (1960).

    Google Scholar 

  11. P. Bouchet, J. Elguero, and R. Jacquier, Bull. Soc. Chim. France, 4716 (1967).

  12. R. M. Powers, J. L. Harper, and Han Tai, Anal. Chem., 32, 1287 (1960).

    Google Scholar 

  13. R. E. Klinck and J. B. Stothers, Can. J. Chem., 40, 1071 (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 250–253, February, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kutulya, L.A., Shevchenko, A.E. & Surov, Y.N. Structures of the products of formylation of 1,3,5-triphenyl- and 1,5 -diphenyl-3-stryl-2-pyrazolines. Chem Heterocycl Compd 11, 215–217 (1975). https://doi.org/10.1007/BF00471403

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00471403

Keywords

Navigation