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Mechanism of the oxidative condensation of acridines with nucleophiles

I. Kinetics of the condensation of acridines with methyl-substituted heterocyclic alkiodides

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of the reaction of acridine hydrochloride with the alkiodides of 2- and 4-picolines, 2- and 4-methylquinolines, 2-methylbenzothiazole, and 1,2-dimethylbenzimidazole in the presence of air oxygen were investigated. It is shown that the reaction is second order overall and first order in each of the components at a constant oxygen concentration. The reaction rate constants were calculated, and a mechanism is proposed for the reaction.

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Authors and Affiliations

  1. S. M. Kirov Ural Polytechnic Institute, Sverdlovsk

    V. E. Kirichenko & O. N. Chupakhin

Authors
  1. V. E. Kirichenko
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  2. O. N. Chupakhin
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No, 5, pp. 675–678, May, 1974.

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Kirichenko, V.E., Chupakhin, O.N. Mechanism of the oxidative condensation of acridines with nucleophiles. Chem Heterocycl Compd 10, 583–586 (1974). https://doi.org/10.1007/BF00471333

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  • DOI: https://doi.org/10.1007/BF00471333

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