Abstract
The polarographic behavior of a number of N-benzylideneiminopyridinium iodides in aqueous alcohol buffer solutions was studied over a wide range of pH values. The mechanism of their reduction on a dropping mercury electrode and the factors affecting the cleavage of the N-N bond are discussed. The reduction product-the pyridinium ion-induces the catalytic evolution of hydrogen.
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T. V. Troepol'skaya and Yu. P. Kitaev, Khim. Geterotsikl. Soedin., 1219 (1973).
P. Tompkins. Anal. Chem., 21, 64 (1949).
S. G. Mairanovskii. Dokl. Akad. Nauk SSSR. 110, 593 (1956).
S. G. Mairanovskii. Dokl. Akad. Nauk SSSR. 114, 1272 (1957).
L. Floch. M. S. Spritzer, and P. J. Elving, Anal. Chem., 38, 1074 (1966).
Yu. P. Kitaev and T. V. Troepol'skaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1903 (1967).
Yu. P. Kitaev, I. M. Skrebkova, and L. I. Maslova, Izv. Akad. Nauk SSSR. Ser. Khim., 2194 (1970).
S. G. Mairanovskii, J. Electroanal. Chem., 12, 547 (1966).
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See [1] for communication XXXVIII.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 666–669, May, 1974.
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Kitaev, Y.P., Troepol'skaya, T.V. & Orlova, L.N. Hydrazones. Chem Heterocycl Compd 10, 576–578 (1974). https://doi.org/10.1007/BF00471331
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DOI: https://doi.org/10.1007/BF00471331