Chemistry of Heterocyclic Compounds

, Volume 11, Issue 9, pp 1018–1019 | Cite as

Synthesis of 5-nitrofuran-2-carboxylic acid

  • G. D. Krapivin
  • L. A. Badovskaya
  • V. G. Kul'nevich
Article

Abstract

5-Nitrofuran-2-carboxylic acid was obtained in quantitative yield by oxidation of 5-nitrofurfural with hydrogen peroxide and decomposition of the intermediate 5-nitrofurfural α-hydroxyhydroperoxide. The mechanism of the reaction is discussed.

Keywords

Oxidation Hydrogen Hydrogen Peroxide Organic Chemistry Quantitative Yield 

Literature cited

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    A. A. Ponomarev, Syntheses and Reactions of Furan Compounds [in Russian], Saratov (1964).Google Scholar
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    G. D. Krapivin, L. A. Badovskaya, and V. G. Kul'nevich, Khim. i Khim. Tekhnol., Trudy KPI, Krasnodar, No. 63, 27 (1974).Google Scholar
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    Ya. É. Eidus, A. Ya. Ékame, K. K. Venter, and S. A. Giller, Atlas of Electronic Spectra of 5-Nitrofuran Compounds [in Russian], Riga (1968), p. 76.Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • G. D. Krapivin
    • 1
  • L. A. Badovskaya
    • 1
  • V. G. Kul'nevich
    • 1
  1. 1.Krasnodar Polytechnic InstituteUSSR

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