Skip to main content
Log in

Hydrogenation of succinimide to pyrrolidin-2-one

I. Influence of the solvent on the catalytic reduction of succinimide

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The influence of the nature of the solvent on the hydrogenation of succinimide over Raney nickel was studied. The greatest rates of reduction of the imide and of the formation of pyrrolidinone were found when alcohols and dioxane were used. An influence of the solvent on the ratio of the rates of the various stages in the synthesis of pyrrolidinone from the imide was found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. Tafel and M. Stern, Ber., 33, 2225, 1900.

    Google Scholar 

  2. B. Sakurai, Bull. Chem. Soc. Japan, 10, 311, 1935.

    Google Scholar 

  3. A. Ladenburg, Ber., 20, 2215, 1887.

    Google Scholar 

  4. V. I. Romanovskii, A. I. Sokolova, and N. I. Tat'yanchikova, Khim. prom., 491, 1963.

  5. US patent no. 3092638, 1963; RZhKh, 9N141P, 1965.

  6. H. Adkins and H. Cramer, J. Am. Chem. Soc., 52, 4349, 1930.

    Google Scholar 

  7. L. M. Rice, E. E. Reid, and C. H. Grogan, J. Org. Chem., 19, 884, 1954.

    Google Scholar 

  8. K. C. Schreiber and V. P. Fernandez, J. Org. Chem., 26, 1744, 1961.

    Google Scholar 

  9. N. E. Vishnevskii, N. P. Glukhanov, and I. S. Kovalev, High-Pressure Apparatus with a Hermetic Drive [in Russian], Mashgiz, 1960.

  10. D. V. Sokol'skii and F. Bizhanov, Vest. AN KazSSR, no. 6, 57, 1961.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Evgrashin, V.M., Ioffe, I.I. & Yakushkin, M.I. Hydrogenation of succinimide to pyrrolidin-2-one. Chem Heterocycl Compd 6, 330–333 (1970). https://doi.org/10.1007/BF00471235

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00471235

Keywords

Navigation