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Grignard reaction with 2, 6-dialkoxydihydro- and -tetrahydropyrans

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The Grignard reaction with 2, 6-dialkoxytetrahydropyran and 2, 6-dialkoxy-5, 6-dihydro-2H-pyran has been studied. In both cases the reaction takes place with the opening of the pyran ring and the formation of alkoxy-substituted saturated or γ, δ-unsaturated alcohols.

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References

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Authors and Affiliations

  1. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    L. N. Kralinina, R. I. Kruglikova & T. P. Tarulina

Authors
  1. L. N. Kralinina
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  2. R. I. Kruglikova
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  3. T. P. Tarulina
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Additional information

During the complption of our work, a paper appeared in which the Grignard reaction with 2, 6-diethoxytetrahydropyran was studied [1].

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Kralinina, L.N., Kruglikova, R.I. & Tarulina, T.P. Grignard reaction with 2, 6-dialkoxydihydro- and -tetrahydropyrans. Chem Heterocycl Compd 6, 290–292 (1970). https://doi.org/10.1007/BF00471222

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  • DOI: https://doi.org/10.1007/BF00471222

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