Chemistry of Heterocyclic Compounds

, Volume 5, Issue 3, pp 360–362 | Cite as

The synthesis and some reactions of thiophene sulfides

XVIII. The synthesis and reactions of 5-alkylthio-4-chloromethyl-2-alkyl-thiophenes
  • Ya. L. Gol'dfarb
  • M. A. Kalik
  • M. L. Kirmalova
Article

Abstract

Chloromethyl ether reacts with alkyl 5-alkyl-2-thienyl sulfides to introduce the chloromethyl group in the 3-position of the thiophene ring. From 5-ethylthio-4-chloromethyl-2-ethylthiophene are prepared derivatives of ethyl 5-ethyl-2-thienyl sulfide with various functional groups in the 3-position.

Keywords

Ether Ethyl Sulfide Organic Chemistry Thiophene 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J. Cymerman-Craig and J. Loder, J. Chem. Soc., 237, 1954.Google Scholar
  2. 2.
    Ya. L. Gol'dfarb and M. S. Kondakova, Izv. AN SSSR, OKhN, 495, 1956.Google Scholar
  3. 3.
    Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, OKhN, 701, 1962.Google Scholar
  4. 4.
    F. Kröhnke, Angew. Chem., 75, 317, 1963.Google Scholar
  5. 5.
    Tyo Sone, Bull. Chem. Soc. Japan, 37, 1197, 1964.Google Scholar
  6. 6.
    V. Traynelis and W. Hergenrother, J. Am. Chem. Soc., 86, 298, 1964.Google Scholar
  7. 7.
    Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, ZhOKh, 29, 2034, 1959.Google Scholar
  8. 8.
    P. Cagniant and P. Cagniant, Bull. Soc. Chim. France, 713, 1952.Google Scholar
  9. 9.
    Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, ser. khim., 1801, 1963.Google Scholar
  10. 10.
    P. A. Lasselle and S. A. Sundet, J. Am. Chem. Soc., 63, 2374, 1941.Google Scholar
  11. 11.
    Ya. L. Gol'dfarb and M. A. Kalik, KhGS [Chemistry of Heterocyclic Compounds], 475, 1969.Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • Ya. L. Gol'dfarb
    • 1
  • M. A. Kalik
    • 1
  • M. L. Kirmalova
    • 1
  1. 1.Zelinskii Institute of Organic ChemistryAS USSRMoscow

Personalised recommendations