Skip to main content
SpringerLink
Log in

Atranes

XVIII. Kinetics of the hydrolysis of 1-alkyl- and 1-alkoxysilatranes

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The kinetics of the hydrolysis of 15 1-alkyl-, 1-alkoxy- and 1-hydrosilatranes in an aqueous medium has been studied. The hydrolysis reaction is described by a first-order kinetic equation. 1-Hydrosilatrane is hydrolyzed most readily and 1-isopropyl- and 1-tert-butoxysilatranes with the greatest difficulty. A correlation has been drawn up of the logarithms of the rate constants of the hydrolysis of the silatranes and the σ* constants of the substituents, the influence of the latter on the reaction has been discussed, and a scheme for its mechanism has been put forward.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. A. Chetverikova, V. A. Kogan, G. I. Zelchan, M. G. Voronkov, and O. A. Osipov, KhGS [Chemistry of Heterocyclic Compounds], 5, 446, 1969.

    Google Scholar 

  2. H. Reuther, Z. anorg. Chem., 272, 122, 1953.

    Google Scholar 

  3. M. G. Voronkov and L. A. Zhagata, Izv. AN Latv. SSR, ser. khim., 452, 1967.

  4. M. G. Voronkov and L. A. Zhagata, ZhOKh, 37, 1156, 2551, 1967.

    Google Scholar 

  5. R. Aelion, A. Loebel, and F. Eirich, J. Am. Chem. Soc., 72, 5705, 1950; Rec. Trav. chim. PaysBas, 69, 61, 1950.

    Google Scholar 

  6. V. A. Vekhov, E. N. Dudnik, and E. I. Rumyantseva, ZhNKh, 10, 2359, 1965.

    Google Scholar 

  7. M. G. Voronkov and G. I. Zelchan, KhGS [Chemistry of Heterocyclic Compounds], 1, 51, 1965.

    Google Scholar 

  8. M. G. Woronkow, G. I. Seltschans, A. F. Lapsina, and W. A. Pestunowitsch, Z. Chem., 8, 214, 1968.

    Google Scholar 

  9. Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Izd-vo RGU, 1966.

  10. Ya. K. Syrkin, Izv. AN SSSR. OKhN, 389, 401, 1959.

    Google Scholar 

  11. R. H. Baney, O. W. Steward, and O. R. Pierce, J. Am. Chem. Soc., 83, 4932, 1961.

    Google Scholar 

  12. V. A. Pal'm, Usp. khim., 30, 1069, 1961; Principles of the Quantitative Theory of Organic Reactions [in Russian], Khimiya, Leningrad, 1967.

    Google Scholar 

  13. I. P. Biryukov, M. G. Voronkov, and I. A. Safin, Izv. AN LatvSSR, ser. khim., 638, 1966.

  14. I. P. Biryukov, M. G. Voronkov, and I. A. Safin, DAN, 165, 857, 1965.

    Google Scholar 

  15. I. P. Biryukov, M. G. Voronkov, and I. A. Safin, TEKh [Theoretical and Experimental Chemistry], 1, 373, 1965.

    Google Scholar 

  16. I. P. Birjukoo and M. G. Voronkov, Intern. Symp. on Organosilicon Chem., Prague, p. 204, 1961.

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis AS Latvian SSR, Riga

    M. G. Voronkov & G. I. Zelchan

Authors
  1. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. I. Zelchan
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For part XVII, see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Voronkov, M.G., Zelchan, G.I. Atranes. Chem Heterocycl Compd 5, 335–338 (1969). https://doi.org/10.1007/BF00471138

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00471138

Keywords

Search

Navigation