Chemistry of Heterocyclic Compounds

, Volume 14, Issue 3, pp 297–300 | Cite as

Reaction of pyridine-2-thione with acetylenes

  • G. G. Skvortsova
  • D. G. Kim
  • L. V. Andriyankova


In contrast to 2-pyridone, pyridine-2-thione reacts with acetylene with the participation of one reaction center — the sulfur atom. The reaction with phenylacetylene and diacetylene proceeds stereospecifically to give products with cis structures. The structures of the synthesized compounds were confirmed by chemical and spectroscopic methods.


Sulfur Organic Chemistry Reaction Center Acetylene Sulfur Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. A. Jones and A. R. Katritzky, J. Chem. Soc., No. 10, 3610 (1958).Google Scholar
  2. 2.
    M. F. Shostakovskii, G. G. Skvortsova, S. M. Tyrina, Yu. L. Frolov, N. M. Deriglazov, V. K. Voronov, and N. A. Ivanova, Dokl. Akad. Nauk SSSR, 186, 620 (1969).Google Scholar
  3. 3.
    O. N. Temkin and R. M. Flid, Catalytic Transformations of Acetylene Compounds in Solutions of Complex Metals [in Russian], Nauka, Moscow, (1968), p. 11.Google Scholar
  4. 4.
    K. Undheim and L. A. Riege, J. Chem. Soc., Perkin Trans. I, No. 15, 1493 (1975).Google Scholar
  5. 5.
    L. J. Bellamy, New Data on the IR Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971), p. 318Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • G. G. Skvortsova
    • 1
  • D. G. Kim
    • 1
  • L. V. Andriyankova
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRIrkutsk

Personalised recommendations