Chemistry of Heterocyclic Compounds

, Volume 11, Issue 8, pp 991–994 | Cite as


XLVI. 2-pyrimidoylacetate esters
  • V. V. Lapachev
  • O. A. Zagulyaeva
  • V. P. Mamaev


The corresponding 2-pyrimidoylacetate esters (I, II) and 2-pyrimidoyl-acetonitrile (V) were obtained by condensation of pyrimidine-2-carboxylic acid esters with methyl acetate or acetonitrile. The structures of the tautomeric forms were determined by IR and PMR spectroscopy. The effect of a solvent and protonation of the pyrimidine ring on the ketone-enol equilibrium was examined.


Spectroscopy Methyl Acetate Ester Organic Chemistry 
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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • V. V. Lapachev
    • 1
  • O. A. Zagulyaeva
    • 1
  • V. P. Mamaev
    • 1
  1. 1.Institute of Organic ChemistryAcademy of Sciences of the USSR, Siberian BranchNovosibirsk

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