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Isomerization of 3-aryl-4-sulfolenes and their reaction with some nucleophilic reagents

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Bases convert 3-(4-substituted phenyl)-4-sulfolenes to 3-aryl-3-sulfolenes, which are subsequently isomerized to 3-aryl-2-sulfolenes. The ratios of the products depend on the character of the substituent in the phenyl ring, and electron-acceptor substituents accelerate the isomerization.

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Literature cited

  1. T. É. Bezmenova, S. M. Lukashov, and Yu. N. Usenko, Khim. Geterotsikl. Soedin., 764 (1973).

  2. M. Prochazka and M. Palacek, Coll. Czech. Chem. Commun., 31, 3744 (1966).

    Google Scholar 

  3. V. West, Applications of Spectroscopy in Chemistry [Russian translation] Moscow (1959), p. 323.

  4. J. Emsley, J. Feeney, and L. Sutcliffe, High-Resolution NMR spectroscopy, Pergamon, Oxford (1965, 1966).

    Google Scholar 

  5. O. V. Sverdlova, Electronic Spectra in Organic Chemistry [in Russian], Khimiya, Leningrad (1973),p. 139.

    Google Scholar 

  6. H. Zimmermanova and M. Prochazka, Coll. Czech. Chem. Commun., 30, 286 (1965).

    Google Scholar 

  7. L. K. Brice, W. M. Chang, J. E. Smith, and S. M. Sullivan, J. Phys. Chem., 71, 2814 (1967).

    Google Scholar 

  8. K. D. Riche and U. F. Sedger in: Modern Problems of Physical Organic Chemistry [Russian translation], Mir, Moscow (1967), p. 498.

    Google Scholar 

  9. C. D. Broaddus, J. Amer. Chem. Soc., 88, 3863 (1966).

    Google Scholar 

  10. N. N. Émanuél' and D. G. Knorre, Course in Chemical Kinetics, [in Russian], Moscow (1969), p. 162.

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Authors and Affiliations

  1. Institute of the Chemistry of Macromolecular-Weight Compounds, Academy of Sciences of the Ukrainian SSR, Kiev

    T. É. Bezmenova, S. M. Lukashov, V. P. Tantsyura, T. S. Lutsii, A. F. Rekasheva & T. D. Zaika

Authors
  1. T. É. Bezmenova
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  2. S. M. Lukashov
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  3. V. P. Tantsyura
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  4. T. S. Lutsii
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  5. A. F. Rekasheva
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  6. T. D. Zaika
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1072–1077, August, 1975.

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Bezmenova, T.É., Lukashov, S.M., Tantsyura, V.P. et al. Isomerization of 3-aryl-4-sulfolenes and their reaction with some nucleophilic reagents. Chem Heterocycl Compd 11, 935–940 (1975). https://doi.org/10.1007/BF00470494

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  • DOI: https://doi.org/10.1007/BF00470494

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