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Beckmann rearrangement of 5-arylfurfural oximes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The acylation of 5-arylfurfural oximes with acetic anhydride in the presence of pyridine is accompanied by Beckmann rearrangement and gives 5-arylpyromucic acid acetamides. Under the same conditions, 5-arylpyromucic acid nitriles are obtained from aldoxime anti-acetates.

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Literature cited

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1026–1029, August, 1975.

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Oleinik, A.F., Vozyakova, T.I., Solov'eva, N.P. et al. Beckmann rearrangement of 5-arylfurfural oximes. Chem Heterocycl Compd 11, 895–897 (1975). https://doi.org/10.1007/BF00470485

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  • DOI: https://doi.org/10.1007/BF00470485

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