Chemistry of Heterocyclic Compounds

, Volume 12, Issue 11, pp 1217–1222 | Cite as

Reactions and mass-spectrometric study of aza analogs of 2-aminochromone

  • O. M. Glozman
  • D. V. Zagorevskii
  • L. A. Zhmurenko
  • V. A. Zagorevskii
Article
  • 25 Downloads

Abstract

Electrophilic substitution reactions at the C and N(2) atoms of 2-amino-4-oxo-4H-pyrano[2,3-b]pyridine were studied, 2-Aminoazachromones were subjected to a massspectroscopic study in comparison with 2-aminochromenes, and fundamental differences in their fragmentation were established.

Keywords

Organic Chemistry Pyridine Fundamental Difference Substitution Reaction Electrophilic Substitution 

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Literature cited

  1. 1.
    L. A. Zhmurenko, O. M. Glozman, and V. A. Zagorevskii, Khim. Geterotsikl. Soedin., No. 12, 1616 (1974).Google Scholar
  2. 2.
    V. A. Zagorevskii, O. M. Glozman, V. G. Vinokurov, and V. S. Troitskaya, Khim. Geterotsikl. Soedin., No. 5, 782 (1967).Google Scholar
  3. 3.
    O. M. Glozman, V. A. Zagorevskii, L. A. Zhmurenko, V. S. Troitskaya, and V. G. Vinokurov, Khim. Geterotsikl. Soedin., Sbornik II. Kislorodsoderzhashchie Geterotsikly (Oxygen-Containing Heterocycles), Riga (1970), p. 143.Google Scholar
  4. 4.
    O. M. Glozman, L. A. Zhmurenko, and V. A. Zagorevskii, Khim.-farm. Zh., No. 5, 17 (1971).Google Scholar
  5. 5.
    O. M. Glozman, N. S. Tolmacheva, L. A. Zhmurenko, and V. A. Zagorevskii, Khim.-farm. Zh., No. 2, 9 (1973).Google Scholar
  6. 6.
    N. Uccella, I. Howe, and D. H. Williams, Org. Mass Spectrom., 6, 229 (1972).Google Scholar
  7. 7.
    C. S. Barnes and J. L. Occolowitz, Austr. J. Chem., 17, 975 (1964).Google Scholar
  8. 8.
    M. M. Badawi, M. B. E. Fayez, T. A. Bryce, and R. I. Read, Chem. Ind., 498 (1966).Google Scholar
  9. 9.
    G. Barker and G. P. Ellis, Org. Mass Spectrom., 5, 857 (1971).Google Scholar
  10. 10.
    Q. N. Porter and J. Baldas, Mass Spectrometry of Heterocyclic Compounds, General Heterocyclic Chemistry Series, edited by A. Weissberger and E. C. Taylor, New York-London-Sidney-Toronto (1971), p. 189.Google Scholar
  11. 11.
    H. G. Viehe and V. Jaeger, Angew. Chem., Inter. Ed., 8, 979 (1969).Google Scholar
  12. 12.
    C. P. Lewis, Anal. Chem., 36, 176 (1964).Google Scholar
  13. 13.
    C. P. Lewis, Anal. Chem., 36, 1582 (1964).Google Scholar
  14. 14.
    Y. B. Thomson, P. B. Brown, and C. Djerassi, J. Amer. Chem. Soc., 88, 4049 (1966).Google Scholar
  15. 15.
    W. E. Pereira, B. Halpern, M. D. Solomon, and A. M. Duffield, Org. Mass Spectrom., 5, 157 (1971).Google Scholar
  16. 16.
    R. T. Aplin and Y. H. Yones, Chem. Commun., 794 (1966).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • O. M. Glozman
    • 1
  • D. V. Zagorevskii
    • 1
  • L. A. Zhmurenko
    • 1
  • V. A. Zagorevskii
    • 1
  1. 1.Scientific-Research Institute of PharmacologyAcademy of Medical Sciences of the USSRMoscow

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