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Reaction of 5-mercapto-1,2,3-triazole-4-carboxamides with phosphorus decasulfide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 5-mercapto-1,2,3-triazole-4-carboxamide with P4S10 was studied; the mechanism of this reaction is discussed. The effect of the donor-acceptor properties of the substituents on the direction of cyclization of the intermediate malonic acid α-diazodithioamide was investigated. A new rearrangement in the 5-mercapto-1,2,3-triazole series was observed.

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Literature Cited

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 827–829, June, 1989.

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Dankova, E.F., Bakulev, V.A., Kolobov, M.Y. et al. Reaction of 5-mercapto-1,2,3-triazole-4-carboxamides with phosphorus decasulfide. Chem Heterocycl Compd 25, 688–690 (1989). https://doi.org/10.1007/BF00470031

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  • DOI: https://doi.org/10.1007/BF00470031

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