Chemistry of Heterocyclic Compounds

, Volume 1, Issue 5, pp 503–507 | Cite as

Tertiary amines and quaternary salts derived from alpha-substituted stilbenes and heterocyclic nitrogen bases

  • K. G. Tashchuk
  • A. V. Dombrovskii
Article
  • 70 Downloads

Abstract

N-bromosuccinimide and α-methylstilbenes, p-methyl-α-chlorostilbene, and p-methyltolan give bromomethyl derivatives, which react with piperidine to give tertiary amines. The latter and methyl iodide give quaternary salts.

With pyridine, γ-picoline, and quinoline, the p-bromomethyl-d-chlorostilbenes synthesized give quaternary bromides which are readily soluble in water and converted into perchlorates by KClO4.

Keywords

Methyl Bromide Pyridine Iodide Perchlorate 

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Copyright information

© The Faraday Press, Inc. 1966

Authors and Affiliations

  • K. G. Tashchuk
    • 1
  • A. V. Dombrovskii
    • 1
  1. 1.Cvernovice State UniversityUSSR

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