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Behaviour of copper(II) and nickel(II) dialkyldithiocarbamates on polar and non-polar stationary phases

Verhalten von Kupfer(II)- und Nickel(II)-dialkyldithiocarbamaten auf polaren und unpolaren stationären Phasen

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Zusammenfassung

Je 15 Dialkyldithiocarbamatkomplexe von Kupfer(II) und Nickel(II) wurden dargestellt und ihre Retentionszeiten auf der unpolaren Phase OV-101 sowie den polaren Phasen NGA und OV-225 gemessen. Die Beziehung zwischen der Retentionscharakteristik der Komplexe und ihrer Struktur wurde untersucht. Es zeigte sich, daß die Länge des Alkylsubstituenten (als sterische Hinderung) die Retention auf der unpolaren Phase beeinträchtigt.

Summary

Fifteen Dialkyldithiocarbamate complexes each of copper(II) and Ni(II) have been prepared and the retention times of these complexes have been measured on the non-polar OV-101 phase and the polar NGA and OV-225 phases. The relationship has been studied between the retention characteristics of the complexes and their structure. The lenght of the alkyl substituent, regarded as a steric hindrance, turned out to affect the retention of the complexes on the non-polar phases.

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Authors and Affiliations

  1. Department of Physical Chemistry, Pharmaceutical Faculty, Medical Academy, K. Marks No. 107, PL-80-416, Gdańsk, Poland

    Jan Halkiewicz, Henryk Lamparczyk & Aleksander Radecki

Authors
  1. Jan Halkiewicz
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  2. Henryk Lamparczyk
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  3. Aleksander Radecki
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Halkiewicz, J., Lamparczyk, H. & Radecki, A. Behaviour of copper(II) and nickel(II) dialkyldithiocarbamates on polar and non-polar stationary phases. Z. Anal. Chem. 320, 577–580 (1985). https://doi.org/10.1007/BF00468951

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  • DOI: https://doi.org/10.1007/BF00468951

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