Fresenius' Zeitschrift für analytische Chemie

, Volume 320, Issue 6, pp 577–580 | Cite as

Behaviour of copper(II) and nickel(II) dialkyldithiocarbamates on polar and non-polar stationary phases

  • Jan Halkiewicz
  • Henryk Lamparczyk
  • Aleksander Radecki
Original Papers


Fifteen Dialkyldithiocarbamate complexes each of copper(II) and Ni(II) have been prepared and the retention times of these complexes have been measured on the non-polar OV-101 phase and the polar NGA and OV-225 phases. The relationship has been studied between the retention characteristics of the complexes and their structure. The lenght of the alkyl substituent, regarded as a steric hindrance, turned out to affect the retention of the complexes on the non-polar phases.


Copper Nickel Analytical Chemistry Inorganic Chemistry Retention Time 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Verhalten von Kupfer(II)- und Nickel(II)-dialkyldithiocarbamaten auf polaren und unpolaren stationären Phasen


Je 15 Dialkyldithiocarbamatkomplexe von Kupfer(II) und Nickel(II) wurden dargestellt und ihre Retentionszeiten auf der unpolaren Phase OV-101 sowie den polaren Phasen NGA und OV-225 gemessen. Die Beziehung zwischen der Retentionscharakteristik der Komplexe und ihrer Struktur wurde untersucht. Es zeigte sich, daß die Länge des Alkylsubstituenten (als sterische Hinderung) die Retention auf der unpolaren Phase beeinträchtigt.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Ahmad M, Aziz A (1978) J Chromatogr 152:542Google Scholar
  2. 2.
    Bor-Kuan Chen, Csaba Horvath (1979) J Chromatogr 171:156Google Scholar
  3. 3.
    Colos VG, Neeb R (1978) Fresenius Z Anal Chem 293:290Google Scholar
  4. 4.
    Daughtrey FH Jr, Fitchett AW, Mushak P (1975) Anal Chim Acta 79:199Google Scholar
  5. 5.
    D'Ascenco G, Wendtland WW (1970) J Inorg Nucl Chem 32:2433Google Scholar
  6. 6.
    Keller R (1973) Anal Chim Acta 63:277Google Scholar
  7. 7.
    Krupčik J, Leclerq PA, Garaj J, Masaryk J (1979) J Chromatogr 171:285Google Scholar
  8. 8.
    Krupčik J, Garaj J, Holotik Š, Octavec P, Košik M (1975) J Chromatogr 112:189Google Scholar
  9. 9.
    Liška O, Lehotay J, Brandsteterovă E, Guiochon G (1979) J Chromatogr 171:153Google Scholar
  10. 10.
    Lucier JJ, Harris AD, Korosec PS (1974) Organic Syntheses 44:72Google Scholar
  11. 11.
    Masaryk J, Krupčik J, Garaj J, Kosik M (1975) J Chromatogr 115:256Google Scholar
  12. 12.
    Radecki A, Halkiewicz J, Grzybowski J, Lamparczyk H (1978) J Chromatogr 151:259Google Scholar
  13. 13.
    Radecki A, Halkiewicz J (1980) J Chromatogr 187:363Google Scholar
  14. 14.
    Riekkola ML (1980) Finn Chem Lett 83Google Scholar
  15. 15.
    Sceney GG, Smith JF, Hill JO, Magee RJ (1976) J Therm Anal 9:6Google Scholar
  16. 16.
    Sceney CG, Magee RJ (1974) Inorg Nucl Chem Lett 10:323Google Scholar
  17. 17.
    Schneider H, Neeb R (1978) Fresenius Z Anal Chem 293:11Google Scholar
  18. 18.
    Sucre L, Jennings W (1980) J High Res Chromatogr, Chromatogr Comm 3:452Google Scholar
  19. 19.
    Tavlaridis A, Neeb R (1976) Z Anal Chem 282:17Google Scholar
  20. 20.
    Tavlaridis A, Neeb R (1978) Fresenius Z Anal Chem 292:135Google Scholar
  21. 21.
    Tavlaridis A, Neeb R (1978) Fresenius Z Anal Chem 292:199Google Scholar
  22. 22.
    Tavlaridis A, Neeb R (1978) Fresenius Z Anal Chem 293:211Google Scholar
  23. 23.
    Varloop A, Hoogenstraaten W, Tripkar J (1977) Drug Res Design 7:165Google Scholar

Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • Jan Halkiewicz
    • 1
  • Henryk Lamparczyk
    • 1
  • Aleksander Radecki
    • 1
  1. 1.Department of Physical Chemistry, Pharmaceutical FacultyMedical AcademyGdańskPoland

Personalised recommendations