Summary
A simple procedure to carry out the direct analysis of calcium, magnesium, sodium and potassium in water by flow injection analysis (FIA) using flame atomic absorption spectroscopy (AAS) or flame photometry (FP) has been developed, using a well stirred dilution chamber to extend the calibration range, and both a double injector and the merging zone technique to add a lanthanum solution to samples and standards. The results obtained in the analysis of real samples agree with those found by a batch flame atomic procedure. The use of the dilution chamber makes it possible to carry out the calibration using the dilution profile of a single concentrate standard for each element, and an empirical dilution equation, which could be employed for all the elements is determined in each work session.
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References
Morel FMM (1983) Principles of aquatic chemistry. J Wiley and Sons, New York
Hem JD (1965) Study and interpretation of the chemical characteristics of natural water. United States Government, Washington
Rodier J (1976) L'analyse de l'eau. Dunod, Paris
Beferull JB, de la Guardia M (1984) Rev Agroquim Tecnol Aliment 24:391–399
Jalfar M, Ashraf M (1986) J Chem Soc Pak 8:49–52
Schinkel H (1984) Z Anal Chem 317:10–26
Ruzicka J, Hansen EH (1988) Flow injection analysis. J Wiley and Sons, New York
Valcarcel M, Luque de Castro MD (1987) Flow injection analysis. Principles and applications. Ellis Horwood, Chichester
Martinez-Jimenez P, Gallego M, Valcarcel M (1987) Anal Chem 59:69–74
De la Guardia M, Salvador A, Burguera JL, Burguera M (1988) J Flow Injection Anal 5:121–131
Burguera JL, Burguera M, Alarcon OM (1986) J Anal At Spectrom 1:79–83
Basson WD, Van Staden JF (1980) Z Anal Chem 302:370–374
Tyson JF, Mariara JR, Appleton JMH (1986) J Anal At Spectrom 1:273–276
Tyson JF (1984) Analyst 109:319–321
Ruzicka J, Hansen EHM (1977) Anal Chim Acta 92:235–249
Gisin M, Thommen C, Mansfield KF (1986) Anal Chim Acta 179:149–167
Stewart KK, Rosenfeld AG (1982) Anal Chem 54:2368–2372
Tyson JF (1985) Analyst 110:419–429
Tyson JF, Appleton JMH (1984) Talanta 31:9–14
Tyson JF, Appleton JMH, Idris AB (1983) Analyst 108:153–158
Tyson JF, Appleton JMH, Idris AB (1983) Anal Chim Acta 145:159–168
Zagatto EAG, Krug FJ, Bergamin FH, Jörgensen SS, Reis BF (1979) Anal Chim Acta 104:279–284
Uchida T, Wei C, Iida C, Wade H (1982) Nagoya Kogyo Daigaku Gakuho 33:97–101
Zhang S, Sung L, Jiang H, Fang Z (1984) Guangpuxue Yu Guangpu Fenxi 4:42–47
Olsen S, Ruzicka J, Hansen EH (1982) Anal Chim Acta 136:101–112
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de la Guardia, M., Carbonell, V., Morales, A. et al. Direct determination of calcium, magnesium, sodium and potassium in water by flow injection flame atomic spectroscopy, using a dilution chamber. Z. Anal. Chem. 335, 975–979 (1989). https://doi.org/10.1007/BF00466392
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DOI: https://doi.org/10.1007/BF00466392