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Stabilitätsbeziehungen von Prehnit- und Pumpellyit-haltigen Paragenesen

Stability relations of parageneses containing prelmite and pumpellyite

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Abstract

This investigation was undertaken to find the typical conditions for the formation of low-grade metamorphic rocks in which prehnite and/or pumpellyite (± actinolite, chlorite, epidote, and quartz) occur as characteristic minerals. In the p, t diagram the slope of the equilibrium curve prehnite + chlorite + H2O=pumpellyite + actinolite + quartz is negative; the slope of the equilibrium curve pumpellyite + chlorite + quartz=epidote + actinolite + H2O is positive. The point of intersection of the two equilibrium curves is an invariant point. The relative positions of the six equilibrium curves surrounding the invariant point were found by applying Schreinemakers's analysis.

Experimental results show that the paragenesis prehnite-pumpellyite-chlorite-quartz is stable at 2 kb up to 345±20 °C, and at 7 Kb up to 260±20 °C. The paragenesis actinolitechlorite-pumpellyite-quartz occurs only at pressures greater than 2.5±1 kb. It is stable at 7 kb in the strongly pressure-dependent temperature range 260±20 °C to 370±20 °C. The paragenesis actinolite-chlorite-epidote-quartz, typical of the greenschist facies, may occur at pressures of 2–3 kb at temperatures of at least 350±20 °C. This temperature limit is only slightly changed with increasing pressure.

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Literatur

  • Althaus, E.: Das System Al2O3-SiO2-H2O. Experimentelle Untersuchungen und Folgerungen für die Petrogenese der metamorphen Gesteine. Neues Jahrbuch Mineral. Abhand. 111, 74–161 (1969).

    Google Scholar 

  • Boettcher, A. S., Wyllie, P. J.: The calcite-aragonite transformation etc. J. Geol. 76, 314–330 (1968).

    Google Scholar 

  • Coombs, D. S.: Lower grade mineral facies in New Zealand. Internat. Geol. Congr. 21st. Copenhagen, Rept. Part 13, 339–351 (1960).

  • —: Some recent work on the lower grades of metamorphism. Australian J. Sci. 24, 203–215 (1961).

    Google Scholar 

  • —, Ellis, A. J., Fyfe, W. S., Taylor, A. M.: The zeolite facies with comments on the interpretation of hydrothermal synthesis. Geochim. Cosmochim. Acta 17, 53–107 (1959).

    Google Scholar 

  • —, Horodyski, R. J., Naylor, R. S.: Occurence of prehnite-pumpellyite facies metamorphism in northern Maine. Am. J. Sci. 268, 142–156 (1970).

    Google Scholar 

  • De Roever, W. P.: Occurence of the mineral pumpellyite in eastern Borneo. Bull. Bor. Min. Indones. 1, 16–17 (1947).

    Google Scholar 

  • Dickinson, W. R.: Petrology and diagenesis of jurassic andesitic strata in central Oregon. Am. J. Sci. 260, 481–500 (1962).

    Google Scholar 

  • Dietrich, V.: Vergleichende Untersuchungen zwischen den Ophiolithen der Platta-Decke259-01 Fortschr. Mineral. 47, Beiheft I, 10–15 (1970).

    Google Scholar 

  • Goldsmith, R. J., Newton, R. C.: P-T-X relations in the system CaCO3-MgCO3 etc. Am. J. Sci. 267A, 160–190 (1969).

    Google Scholar 

  • Hashimoto, M.: On the prehnite-pumpellyite facies. Geol. Soc. Japan J. 72, 253–265 (1965).

    Google Scholar 

  • Hawkins, J. W.: Prehnite-pumpellyite facies metamorphism of a greywacke-shale series, Mount Olympus, Washington. Am. J. Sci. 265, 798–818 (1967).

    Google Scholar 

  • Hinrichsen, Th., Schürmann, K.: Synthese und Bildungsbedingungen des Pumpellyits. Naturwissenschaften 55, 131–132 (1968).

    Google Scholar 

  • — —: Reaktionen zur Festlegung des Stabilitätsfeldes von Pumpellyit. Naturwissenschaften 56, 326 (1969a).

    Google Scholar 

  • — —: Untersuchungen zur Stabilität von Pumpellyit. Neues Jahrb. Mineral. Monatsh. 10, 441–445 (1969b).

    Google Scholar 

  • Hutton, C. O.: On occurrence of the mineral pumpellyite in the Lake Wakatipu region, Western Otago, New Zealand. Mineral. Mag. 24, 529–533 (1937).

    Google Scholar 

  • Landis, C. A., Rogers, J.: Some experimental data on the stability of pumpellyite. Am. Mineralogist 53, 1038–1041 (1968).

    Google Scholar 

  • Levi, B.: Burial metamorphism of a cretaceous volcanic sequence west from Santiago, Chile. Contr. Mineral. and Petrol. 24, 30–49 (1969).

    Google Scholar 

  • Martini, J., Vuagnat, M.: Metamorphose niedrigst temperierten Grades in den Westalpen. Fortschr. Mineral. 47, 51–64 (1970).

    Google Scholar 

  • — —: Metamorphose niedrigst temperierten Grades in den Westalpen. Fortschr. Mineral. 47, Beih. 1, 41–42 (1970).

    Google Scholar 

  • Newton, R. C., Smith, J. V.: Investigations concerning the breakdown of albite at depth in the earth. J. Geol. 75, 268–286 (1967).

    Google Scholar 

  • Niggli, P.: Gesteine und Minerallagerstätten, Vol. 1. Basel 1948.

  • Nitsch, K. H.: Die Stabilität von Lawsonit. Naturwissenschaften 55, 388 (1968).

    Google Scholar 

  • Nockolds, S. R.: Average chemical compositions of some igneous rocks. Geol. Soc. Am. Bull. 65, 1007–1032 (1954).

    Google Scholar 

  • Otalora, G.: Zeolites and related minerals in cretaceous rocks of east central Puerto Rico. Am. J. Sci. 262, 726–734 (1964).

    Google Scholar 

  • Packham, G. H., Crook, K. A. W.: The principle of diagenetic facies and some of its implications. J. Geol. 68, 392–407 (1960).

    Google Scholar 

  • Pettijohn, F. J.: Chemical composition of sandstones excluding carbonate and volcanic sands. In Fleischer, M., ed. Data of geochemistry. U. S. Geol. Surv. Profess. Papers 440-S, 19 (1963).

  • Seki, Y.: Jadeite and associated minerals in meta-gabbroic rocks of Sanbagawa metamorphic belt in Central Japan. Am. Mineralogist 45, 668–679 (1960a).

    Google Scholar 

  • —: Jadeite in the Sanbagawa metamorphic belt of central Japan. Am. J. Sci. 258, 705–715 (1960b).

    Google Scholar 

  • —: Pumpellyite in low-grade metamorphism. J. Petrol. 2, 407–423 (1961).

    Google Scholar 

  • —: Prehnite in low-grade metamorphism. Saitama Univ. Sci. Rept. 13, 5, 29–43 (1965).

    Google Scholar 

  • —, Oki, Y., Matsuda, T., Mikami, K., Okumura, K.: Metamorphism in the Tanzawa Mountains, central Japan. Jap. Assoc. Miner., Petrol. and Econ. Geol. J. 61, 1–75 (1969).

    Google Scholar 

  • Smith, R. E.: Zones of progressive regional burial metamorphism in part of the Tasman geosyncline, eastern Australia. J. Petrol. 10, 144–163 (1969).

    Google Scholar 

  • Strens, R. G. J.: Reconnaissance of the prehnite stability field. Mineral. Mag. 36, 864–867 (1968).

    Google Scholar 

  • Vance, J. A.: Metamorphic aragonite in the prehnite-pumpellyite facies, north-west Washington. Am. J. Sci. 266, 299–315 (1968).

    Google Scholar 

  • Wedepohl, K. H.: Geochemie (Sammlung Göschen). Berlin: Walter de Gruyter 1967.

    Google Scholar 

  • Winkler, H. G. F.: Die Genese der metamorphen Gesteine. Berlin-Heidelberg-New York: Springer 1967.

    Google Scholar 

  • - Abolition of metamorphic facies, introduction of metamorphic stage, and of a classification based on isograds in common rocks. Neues Jahrb. H. 5, 189–248 (1970).

  • Zen, E.-An.: Construction of pressure-temperature diagrams for multicomponent system after the method of Schreinemakers — a geometric approach. Geological Survey Bulletin 1225 (1966).

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Herrn Prof. Dr. H. G. F. Winkler möchte ich an dieser Stelle für die kritische Durchsicht des Manuskriptes sowie manche wertvolle Diskussion danken. Ebenso gilt mein Dank Herrn Dr. B. Storre und Herrn Doz. Dr. P. Metz für anregende Diskussionen. Herr Dr. P. Süße besorgte die Übersetzung des Abstracts.

Außerdem sei den Angestellten der Mineralogischen Anstalten und des Mineralogisch-Petrologischen Instituts gedankt, die zu dieser Arbeit einen Beitrag geleistet haben. Die Deutsche Forschungsgemeinschaft förderte durch apparative Unterstützung wesentlich den experimentellen Teil der vorliegenden Publikation.

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Nitsch, K.H. Stabilitätsbeziehungen von Prehnit- und Pumpellyit-haltigen Paragenesen. Contr. Mineral. and Petrol. 30, 240–260 (1971). https://doi.org/10.1007/BF00455673

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  • DOI: https://doi.org/10.1007/BF00455673

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