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Application of an indicating system of bismuth electrodes for the determination of organic bases and acids in nonaqueous solutions

Anwendung eines Indikationssystems aus Wismutelektroden zur Bestimmung von organischen Basen und Säuren in nichtwäßrigen Lösungen

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Zusammenfassung

Tertiäre Amine und Salze organischer Säuren werden durch Titration mit einer Lösung von Perchlorsäure quantitativ bestimmt. Das verwendete Indicatorsystem besteht aus einem Paar polarisierter oder nichtpolarisierter Wismutelektroden. Das gleiche System wurde auch angewandt auf die titrimetrische Bestimmung von Mono- und Polycarbonsäuren mit einer starken Base. Die Ergebnisse stimmen gut mit denen der potentiometrischen bzw. katalytisch-thermometrischen Methode überein.

Summary

Tertiary amines and salts of organic acids have been titrated by means of perchloric acid applying a biamperometric indicating system consisting of a polarised or unpolarised pair of bismuth electrodes. Also, mono- and polycarboxylic acids, alone and in mixtures, have been determined with a strong base using the same end-point detection technique. The results obtained are in good agreement with those of potentiometry or catalytic thermometry.

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References

  1. Enoki, T., Morisaka, K.: J. Pharm. Soc. Japan 77, 121, 125 (1957); cf. Z. Anal. Chem. 160, 368 (1958).

    CAS  Google Scholar 

  2. Jovanović, M. S., Babić, R.: Bull. Soc. Chim. Beograd 29, 13 (1964).

    Google Scholar 

  3. —, Bakale, D.: Z. Anal. Chem. 244, 101 (1969).

    Article  Google Scholar 

  4. —, Bjelica, L. J., Marinković, A.: Bull. Soc. Chim. Beograd 34, 435 (1969).

    Google Scholar 

  5. Stock, J. T., Purdy, W. C.: Chemist-Analyst 47, 38 (1958); cf. Z. Anal. Chem. 168, 50 (1959).

    Google Scholar 

  6. Vajgand, V., Gaál, F. F.: Talanta 14, 345 (1967); cf. Z. Anal. Chem. 233, 290 (1968).

    Article  CAS  Google Scholar 

  7. — —, Brusin, S. S.: Talanta 17, 415 (1970).

    Article  CAS  Google Scholar 

  8. —, Pastor, T.: a)Bull. Soc. Chim. Beograd 28, 73 (1963); b) J. Electroanal. Chem. 8, 49 (1964); cf. Z. Anal. Chem. 215, 298 (1966).

    CAS  Google Scholar 

  9. —, Todorovski, J. T., Gaál, F. F.: Bull. Soc. Chim. Beograd 33, 293 (1968).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Technology and Metallurgy, Institute of Analytical Chemistry, University of Beograd, Yugoslavia

    Momir S. Jovanović

  2. Faculty of Sciences, Department of Chemistry, University of Novi Sad, Yugoslavia

    Ferenc F. Gaál & Luka J. Bjelica

Authors
  1. Momir S. Jovanović
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  2. Ferenc F. Gaál
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  3. Luka J. Bjelica
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Jovanović, M.S., Gaál, F.F. & Bjelica, L.J. Application of an indicating system of bismuth electrodes for the determination of organic bases and acids in nonaqueous solutions. Z. Anal. Chem. 255, 277–280 (1971). https://doi.org/10.1007/BF00424195

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  • DOI: https://doi.org/10.1007/BF00424195

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