, Volume 69, Issue 3, pp 273–290 | Cite as

Controversies and existence claims in chemistry: The theory of resonance

  • Hans P. W. Vermeeren
The Philosophy Of Chemistry


Controversies, i.e., multiple theory confrontations, may have a strong impact on the development of science. By an analysis of the so-called “resonance controversy” in chemistry the view that controversies and their resolution differ considerably from the process of theory succession is defended. It is argued that controversies are symptomatic of foundational problems, produce theory-scattering or domain-splitting, and induce ontological shifts. An explication is given of the role of existence claims and the applicability of Ockham's Razor in the resolution of controversies. The requirement of a realistic interpretation of theories at all times, as defended by some philosophers, is criticised.


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  1. Allen, J., A. E. Oxford, R. Robinson, and J. C. Smith: 1926, ‘Mesomerism’, Journal of the Chemical Society 1926, 401–411.Google Scholar
  2. Arndt, F., E. Scholz, and F. Nachtwey: 1924, ‘Uber Dipyrilene und über die Bindungsverhältnisse in Pyron-Ringsystemen’, Berichte 57, 1903–1911.Google Scholar
  3. Arndt, F.: 1930, ‘Gleichgewicht und “Zwischenstufe”’, Berichte 63, 2963–2966.Google Scholar
  4. Bantz, D. A.: 1980, ‘The Structure of Discovery: Evolution of Structural Accounts of Chemical Bonding’, Boston Studies in the Philosophy of Science 60, Reidel, Dordrecht.Google Scholar
  5. Brown, H. I.: 1979, ‘A Functional Analysis of Scientific Theories’, Zeitschrift für allgemeine Wissenschaftstheorie 10, 119–140.Google Scholar
  6. Chelintsev, G. V.: 1949, Essays on the Theory of Organic Chemistry, Moscow.Google Scholar
  7. Feyerabend, P.: 1978, Against Method, Verso, London.Google Scholar
  8. Gleicher, G. J. and P. von R. Schleyer: 1967, ‘Homoaromaticity and Non-Classical Ions’, Journal of the American Chemical Society 89, 586–591.Google Scholar
  9. Graham, L. R.: 1971, Science and Philosophy in the Soviet Union, Allen Lane, London.Google Scholar
  10. Ingold, C. K.: 1933, ‘Significance of Tautomerism and of the Reactions of Aromatic Compounds in the Electronic Theory of Organic Reactions’, Journal of the Chemical Society 1933, 1120–1127.Google Scholar
  11. Ihde, A. J.: 1964, The Development of Modern Chemistry, Harper & Row, New York.Google Scholar
  12. Koertge, N.: 1971, ‘Intertheoretic Criticism and the Growth of Science’, Boston Studies in the Philosophy of Science 8, 160–174.Google Scholar
  13. Kosolapoff, G. M.: 1952, Chemical and Engineering News 30, 2474.Google Scholar
  14. Kursanov, D. N., M. G. Gonikberg, B. M. Dubinin, M. I. Kabachnik, E. D. Kaverzneva, E. N. Priliezhaeva, N. D. Sokolov and R. Kh. Freidlana: 1952, ‘The Present State of the Chemical Structural Theory’, Journal of Chemical Education 29, 2–14.Google Scholar
  15. Krüger, L.: 1980, ‘Intertheoretic Relations as a Tool for the Rational Reconstruction of Scientific Development’, Studies in the History and Philosophy of Science 11, 89–101.Google Scholar
  16. Langmuir, I.: 1919, ‘The Arrangement of Electrons in Atoms and Molecules’, Journal of the American Chemical Society 41, 868–934.Google Scholar
  17. Langmuir, I.: 1920, ‘The Octet Theory of Valence and its Applications with Special Reference to Organic Nitrogen Compounds’, Journal of the American Chemical Society 42, 274–292.Google Scholar
  18. Lewis, G. N.: 1916, ‘The Atom and the Molecule’, Journal of the American Chemical Society 38, 762–785.Google Scholar
  19. Lugg, A.: 1980, ‘Theory Choice and Resistance to Change’, Philosophy of Science 47, 227–243.Google Scholar
  20. Pauling, L.: 1931, ‘The Nature of the Chemical Bond’, Journal of the American Chemical Society 53, 1367–1400.Google Scholar
  21. Pauling, L. and G. W. Wheland: 1933, ‘The Quantummechanical Calculation of the Resonance Energy of Benzene and Naphtalene and the Hydrocarbon Free Radicals’, Journal of Chemistry and Physics 1, 362–374.Google Scholar
  22. Pauling, L.: 1939, The Nature of the Chemical Bond, Cornell University Press, Ithaca, New York.Google Scholar
  23. Shapere, D.: 1969, ‘Notes Toward a Post-Positivistic Interpretation of Science’, in P. Achinstein and S. Barker (eds.), The Legacy of Logical Positivism, John Hopkins, Baltimore, pp. 115–160.Google Scholar
  24. Shapere, D.: 1977, ‘Scientific Theories and Their Domains’, in F. Suppe (ed.), The Structure of Scientific Theories, University of Illinois Press, Urbana, pp. 518–565.Google Scholar
  25. Sober, E.: 1981, ‘The Principle of Parsimony’, British Journal for the Philosophy of Science 32, 145–156.Google Scholar
  26. Tatevskii, V. M. and M. I. Shakhparonov: 1949, ‘On a Machist Theory in Chemistry and its Propagandists’, Voprosy Filosofii 3, 176–192.Google Scholar
  27. Van Spronsen, J. W.: 1969, The Periodic System of Chemical Elements, Elsevier, Amsterdam.Google Scholar
  28. Wheland, G. W.: 1944, The Theory of Resonance and its Application to Organic Chemistry, John Wiley, New York.Google Scholar
  29. Wheland, G. W.: 1955, Resonance in Organic Chemistry, John Wiley, New York.Google Scholar

Copyright information

© D. Reidel Publishing Company 1986

Authors and Affiliations

  • Hans P. W. Vermeeren
    • 1
  1. 1.Gorlaeus LaboratoriesLeiden UniversityLeidenThe Netherlands

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