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Rapid chemical reaction in a laminar boundary layer

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Summary

A method is presented for determining the velocity, temperature, and concentration distributions as well as the position of the reaction zone near the surface of a burning fuel. The reaction is assumed to occur in the compressible laminar boundary layer on a flat plate. Variations in properties are allowed for subject to the requirements that the Prandtl and Schmidt numbers equal one and the density-viscosity product is a constant. A method is given for transforming from the boundary layer to the real coordinate system.

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Abbreviations

a, b :

stoichiometric coefficients

a 1, a 2, b 1, b 2 :

constants

B :

transfer parameter, dimensionless

c :

concentration parameter, dimensionless

C :

concentration, g component/g mixture

C P :

specific heat at constant pressure, cal/g°C

D :

diffusivity, cm2/s

f :

velocity boundary layer parameter, dimensionless

h :

enthalpy parameter, dimensionless

H :

specific enthalpy, cal/g or ergs/g

ΔH :

heat of reaction, cal/g oxidant (B)

\(\bar H\) :

partial specific enthalpy. cal/g or ergs/g

J :

mass flux, g/cm2/s

k :

thermal conductivity, cal/cms°C

p :

pressure, dynes/cm2

P :

Prandtl number, dimensionless

Q :

heat loss, cal/g fuel (A) evaporating

S :

Schmidt number, dimensionless

t :

time, s

T :

temperature, °C

u :

velocity in x direction, dimensionless

U :

velocity in x direction, cm/s

v :

velocity in y direction, dimensionless

V :

velocity in y direction, cm/s

x :

direction parallel to plate, cm

y :

direction perpendicular to plate, cm

η :

boundary layer coordinate, dimensionless

λ :

heat of vaporization, cal/g

μ :

viscosity, g/cms

ν :

kinematic viscosity, cm2/s

ρ :

density, g/cm3

A :

fuel or surface side of reaction zone

B :

oxidant or mainstream side of reaction zone

C :

concentration

i :

species i

M :

mainstream conditions

R :

reaction zone conditions

S :

surface conditions

T :

thermal

References

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  2. Spalding, D. B., The Combustion of Liquid Fuels, Fourth Symposium (International) on Combustion, Williams and Wilkins, Balto., 1953, p. 847.

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  4. Bird, R. B., Theory of Diffusion, Advances in Chemical Engineering, edited by T. B. Drew and J. W. Hoopes Jr., Academic Press, New York, 1956.

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Friedlander, S.K., Litt, M. Rapid chemical reaction in a laminar boundary layer. Appl. sci. Res. 8, 403–412 (1959). https://doi.org/10.1007/BF00411766

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  • DOI: https://doi.org/10.1007/BF00411766

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