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Collisional narrowing and spectral shift in coherent anti-stokes Raman spectra of molecular nitrogen up to 2500 bar and 700 K

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Abstract

CARS spectra of the N2 Q-branch up to 2500 bar and 700 K have been measured. Calculated spectra based on theoretical models show significant disagreement with measured spectra above 300 bar so that CARS temperature measurements are in error by 130 K at 700 K and −150 K at 295 K. The spectral shift of the Q-branch reaches an asymptotic value corresponding to that measured in liquid nitrogen.

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Authors and Affiliations

  1. Physikalisch-Chemisches Institut der Universität, Im Neuenheimer Feld 253, D-6900, Heidelberg, Fed. Rep. Germany

    Th. Bouché, Th. Dreier, B. Lange & J. Wolfrum

  2. Institut für Physikalische Chemie, Universität Karlsruhe, Kaiserstrasse 12, D-7500, Karlsruhe 1, Fed. Rep. Germany

    E. U. Franck & W. Schilling

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  1. Th. Bouché
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  2. Th. Dreier
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  3. B. Lange
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  4. J. Wolfrum
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  5. E. U. Franck
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  6. W. Schilling
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Bouché, T., Dreier, T., Lange, B. et al. Collisional narrowing and spectral shift in coherent anti-stokes Raman spectra of molecular nitrogen up to 2500 bar and 700 K. Appl. Phys. B 50, 527–533 (1990). https://doi.org/10.1007/BF00408779

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  • DOI: https://doi.org/10.1007/BF00408779

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