Abstract
An oligomer solution was prepared from methyltriethoxysilane with HNO3 catalyst. Aluninum acetylacetonate was introudced into the solution to eliminate crystalline precipitates (CH3SiO3/2)8. Self-sustained film was attempted by dropping the solution onto an aqueous solution, into which NaCl was added to elevate the solution density. The film formation greatly depended both on the reaction time and on the supporting solution. The structure of the film thus obtained was investigated by FTIR attenuated total reflectance spectroscopy.
Similar content being viewed by others
References
S. Sakka, in Treatise on Materials Science and Technology, edited by M. Tomozawa and R.H. Doremus (Academic Press, New York, 1982), Vol. 22, p. 129.
M. Yamane, S. Shibata, A. Yasumori, T. Yano, and S. Uchihiro, J. Sol-Gel Sci. Tech. 2, 457 (1994).
Z. Zhang, Y. Tanigami, R. Terai, and H. Wakabayashi J. Non-Cryst. Solids 189, 212 (1995).
Z. Zhang, Y. Tanigami, and R. Terai, J. Non-Cryst. Solids 191, 304 (1995).
Z. Zhang et al., unpublished data.
M. Voronkov and V.I. Lavrent'yev, Topics Current Chem. 102, 199 (1982).
L. Vogt and J.F. BrownJr., Inorg. Chem. 2, 189 (1963).
K. Kamiya, S. Sakka, and M. Mizutani, Yogyo Kyokai-Shi 86, 552 (1978).
A. Duran J.M. Fernanadez-Navarro, P. Casariego, and A. Joglar, J. Non-Cryst. Solids 82, 69 (1982).
J.F. BrownJr., J. Am. Chem. Soc. 87, 4317 (1965).
L.J. Tyler, J. Am. Chem. Soc. 77, 770 (1955).
H. Kita, in Glass Handbook, edited by S. Sakka et al. (Asakura Syoten, Tokyo, 1975), p. 416.
T. Minami and N. Tohge, Hybrids 7, 15 (1991).
A.J. Barry, W.H. Daudt, J.J. Domicone, and J.W. Gilkey, J. Am. Chem. Soc. 77, 4248 (1955).
P. Innocenzi and H. Kozuka, J. Sol-Gel Sci. Tech. 3, 229 (1994).
K. Izumi, H. Tanaka, Y. Uchida, N. Toghe, and T. Minami, J. Non-Cryst. Solids 147/148, 486 (1992).
H. Zhang and C.G. Pantano, J. Am. Ceram. Soc. 73, 958 (1990).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zhang, Z., Tanigami, Y. & Terai, R. Preparation of CH3SiO3/2 film from methyltriethoxysilane. J Sol-Gel Sci Technol 6, 273–278 (1996). https://doi.org/10.1007/BF00402699
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00402699