Abstract
Mixed metal oxides are discussed as possible substitutes for noble metals in automobile catalytic converters. The catalytic activity for CO oxidation of LaMnO3 and La0.5Sr0.5MnO3 catalysts was examined.
The ability of these catalysts to provide lattice oxygen and to sustain the oxidation reaction, even in the absence of molecular oxygen, has been confirmed. Measurements were performed of the reversible oxygen uptake on the two catalysts.
Similar content being viewed by others
References
Carberry, J. J., Rajadurai, S., Alcock, C. B. and Li, B.: 1990, ‘Solid Oxide Solutions—A Comparison with Supported Pt’, Cat. Lett. 4, 43–48.
Chuah, G. K., Jaenicke, S. and Lee, J. Y.: 1991, ‘Steady State Multiplicity in Carbon Monoxide Oxidation over LaMnO3’, Applied Cat. 72, 51–61.
Gallagher, P. K., Johnson Jr., D. W., and Schrey, F.: 1974, ‘Studies of Some Supported Perovskite Oxidation Catalysts’, Mat. Res. Bull. 9, 1345–1352.
Greek, B. F.: 1989, ‘Process Catalysts Enjoy Surging Market’, Chemical & Engineering News, May 29, 29–56.
Johnson, D. W., Gallagher, P. K., Schrey, F., Rhodes, W. W.: 1976, ‘Preparation of High Surface Area Substituted LaMnO3 Catalysts’ Am. Ceram. Soc. Bull. 55(5), 520–523.
Kim, G.: 1982, ‘Ceria-Promoted Three-Way Catalyst for Auto Exhaust Emission Control’, Ind. Eng. Chem. Prod. Res. Dev. 21, 267–274.
Libby, W. F.: 1971, ‘Promising Catalyst for Auto Exhaust’, Science 171, 499–500.
Meadowcraft, D. B.: 1970, ‘Low-Cost Oxygen Electrode Material’, Nature 226, 847–848.
Nakamura, T., Misono, M., and Yoneda, Y.: 1982, ‘Catalytic Properties of Perovskite-Type Mixed Oxides La1-x Sr x CoO3’, Bull. Chem. Soc. Jpn. 55 394–399.
Nakamura, T., Misono, M., and Yoneda, Y.: 1983, ‘Reduction-Oxidation and Catalytic Properties of La1-x Sr x CoO3’, J. Catal. 83, 151–159.
Shelef, M., Otto, K., and Otto, N. C.: 1978, ‘Poisoning of Automotive Catalysts’, Advances in Catalysis 27, D. D. Eley, H. Pines and P.B. Weisz (eds.), Academic Press, New York, 1978, 311–365.
Shyu, J.Z., Otto, K., Watkins, W.L.H., Belitz, R.K., and Gandhi, H.S.: 1988, ‘Characterization of Pd/γ-Alumina Catalysts Containing Ceria’, J. Catal. 114, 23–33.
Snyder, T.P. and Hill, C.G.: 1989, ‘The Mechanism for the Partial Oxidation of Propylene over Bismuth Molybdate Catalysts’, Catal. Rev.-Sci. Eng. 31, 43–95.
Takasu, Y., Matsui, M., and Matsuda, Y.: 1982, ‘The Catalytic Contribution of the Lattice Oxygen Atoms of Praseodymium Oxide to the Oxidation of Carbon Monoxide’, J. Catal. 76, 61–64.
Taylor, K. C.: 1984, ‘Automobile Catalytic Converters’ in: Catalysis-Science and Technology 5, J. R. Anderson and M. Boudart (Eds.), Springer-Verlag, Berlin, pp. 120–170.
Veprek, S., Cocke, D. L., Kehl, S., and Oswald, H. R.: 1986, ‘Mechanism of the Deactivation of Hopcalite Catalysts Studied by XPS, ISS, and Other Techniques’, J. Catal. 100, 250–263.
Voorhoeve, R. J. H.: 1977, ‘Perovskite-Related Oxides asOxidation-Reduction Catalysts’, Advanced Materials in Catalysis, J. J. Barton and R. L. Garten (Eds.), Academic Press, N. Y., pp. 129–180.
Yakel Jr., H. L.: 1955, ‘On the Structures of some Compounds of the Perovskite Type’, Acta Cryst. 8, 394–398.
Yao, Y.-F. Y.: 1975a, ‘The Oxidation of Hydrocarbons and CO over Metal Oxides’, J. Catal. 36, 266–275.
Yao, Y.-F. Y.: 1975b, ‘The Oxidation of CO and C2H4 over Metal Oxides—Part V: SO2 Effects’, J. Catal. 39, 104–114.
Zhang, H. M., Shimizu, Y., Teraoka, Y., Miura, N., and Yamazoe, N.: 1990, ‘Oxygen Sorption and Catalytic Properties of La1-x Sr x Co1-y Fe y O3 Perovskite-Type Oxides’, J. Catal. 121, 432–440.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jaenicke, S., Chuah, G.K. & Lee, J.Y. Catalytic CO oxidation over manganese-containing perovskites. Environ Monit Assess 19, 131–138 (1991). https://doi.org/10.1007/BF00401304
Issue Date:
DOI: https://doi.org/10.1007/BF00401304