Skip to main content
Log in

Catalytic CO oxidation over manganese-containing perovskites

  • Waste Management
  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

Mixed metal oxides are discussed as possible substitutes for noble metals in automobile catalytic converters. The catalytic activity for CO oxidation of LaMnO3 and La0.5Sr0.5MnO3 catalysts was examined.

The ability of these catalysts to provide lattice oxygen and to sustain the oxidation reaction, even in the absence of molecular oxygen, has been confirmed. Measurements were performed of the reversible oxygen uptake on the two catalysts.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Carberry, J. J., Rajadurai, S., Alcock, C. B. and Li, B.: 1990, ‘Solid Oxide Solutions—A Comparison with Supported Pt’, Cat. Lett. 4, 43–48.

    Google Scholar 

  • Chuah, G. K., Jaenicke, S. and Lee, J. Y.: 1991, ‘Steady State Multiplicity in Carbon Monoxide Oxidation over LaMnO3’, Applied Cat. 72, 51–61.

    Google Scholar 

  • Gallagher, P. K., Johnson Jr., D. W., and Schrey, F.: 1974, ‘Studies of Some Supported Perovskite Oxidation Catalysts’, Mat. Res. Bull. 9, 1345–1352.

    Google Scholar 

  • Greek, B. F.: 1989, ‘Process Catalysts Enjoy Surging Market’, Chemical & Engineering News, May 29, 29–56.

  • Johnson, D. W., Gallagher, P. K., Schrey, F., Rhodes, W. W.: 1976, ‘Preparation of High Surface Area Substituted LaMnO3 Catalysts’ Am. Ceram. Soc. Bull. 55(5), 520–523.

    Google Scholar 

  • Kim, G.: 1982, ‘Ceria-Promoted Three-Way Catalyst for Auto Exhaust Emission Control’, Ind. Eng. Chem. Prod. Res. Dev. 21, 267–274.

    Google Scholar 

  • Libby, W. F.: 1971, ‘Promising Catalyst for Auto Exhaust’, Science 171, 499–500.

    Google Scholar 

  • Meadowcraft, D. B.: 1970, ‘Low-Cost Oxygen Electrode Material’, Nature 226, 847–848.

    Google Scholar 

  • Nakamura, T., Misono, M., and Yoneda, Y.: 1982, ‘Catalytic Properties of Perovskite-Type Mixed Oxides La1-x Sr x CoO3’, Bull. Chem. Soc. Jpn. 55 394–399.

    Google Scholar 

  • Nakamura, T., Misono, M., and Yoneda, Y.: 1983, ‘Reduction-Oxidation and Catalytic Properties of La1-x Sr x CoO3’, J. Catal. 83, 151–159.

    Google Scholar 

  • Shelef, M., Otto, K., and Otto, N. C.: 1978, ‘Poisoning of Automotive Catalysts’, Advances in Catalysis 27, D. D. Eley, H. Pines and P.B. Weisz (eds.), Academic Press, New York, 1978, 311–365.

    Google Scholar 

  • Shyu, J.Z., Otto, K., Watkins, W.L.H., Belitz, R.K., and Gandhi, H.S.: 1988, ‘Characterization of Pd/γ-Alumina Catalysts Containing Ceria’, J. Catal. 114, 23–33.

    Google Scholar 

  • Snyder, T.P. and Hill, C.G.: 1989, ‘The Mechanism for the Partial Oxidation of Propylene over Bismuth Molybdate Catalysts’, Catal. Rev.-Sci. Eng. 31, 43–95.

    Google Scholar 

  • Takasu, Y., Matsui, M., and Matsuda, Y.: 1982, ‘The Catalytic Contribution of the Lattice Oxygen Atoms of Praseodymium Oxide to the Oxidation of Carbon Monoxide’, J. Catal. 76, 61–64.

    Google Scholar 

  • Taylor, K. C.: 1984, ‘Automobile Catalytic Converters’ in: Catalysis-Science and Technology 5, J. R. Anderson and M. Boudart (Eds.), Springer-Verlag, Berlin, pp. 120–170.

    Google Scholar 

  • Veprek, S., Cocke, D. L., Kehl, S., and Oswald, H. R.: 1986, ‘Mechanism of the Deactivation of Hopcalite Catalysts Studied by XPS, ISS, and Other Techniques’, J. Catal. 100, 250–263.

    Google Scholar 

  • Voorhoeve, R. J. H.: 1977, ‘Perovskite-Related Oxides asOxidation-Reduction Catalysts’, Advanced Materials in Catalysis, J. J. Barton and R. L. Garten (Eds.), Academic Press, N. Y., pp. 129–180.

    Google Scholar 

  • Yakel Jr., H. L.: 1955, ‘On the Structures of some Compounds of the Perovskite Type’, Acta Cryst. 8, 394–398.

    Google Scholar 

  • Yao, Y.-F. Y.: 1975a, ‘The Oxidation of Hydrocarbons and CO over Metal Oxides’, J. Catal. 36, 266–275.

    Google Scholar 

  • Yao, Y.-F. Y.: 1975b, ‘The Oxidation of CO and C2H4 over Metal Oxides—Part V: SO2 Effects’, J. Catal. 39, 104–114.

    Google Scholar 

  • Zhang, H. M., Shimizu, Y., Teraoka, Y., Miura, N., and Yamazoe, N.: 1990, ‘Oxygen Sorption and Catalytic Properties of La1-x Sr x Co1-y Fe y O3 Perovskite-Type Oxides’, J. Catal. 121, 432–440.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jaenicke, S., Chuah, G.K. & Lee, J.Y. Catalytic CO oxidation over manganese-containing perovskites. Environ Monit Assess 19, 131–138 (1991). https://doi.org/10.1007/BF00401304

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00401304

Keywords

Navigation