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Forced crystallization of poly(1,5-di-oxapene-2-one)-Fe(III) chloride complex onto NaCl surface by polymerizing pyrrole

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Summary

A novel polymer poly(1,5-di-oxepane-2-one) (PDXO) forms with iron(III) chloride a coordination complex, which is a highly viscous liquid. This complex initiates the vapour phase polymerization of pyrrole. The nucleation process of polypyrrole forces crystallization of the PDXO−FeCl3 complex. This crystallization process occurs only on the surface of NaCl.

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Authors and Affiliations

  1. Department of Polymer Technology, Royal Institute of Technology, S-10044, Stockholm, Sweden

    Jan F. Rabek, Julia Lucki & Henryk Kereszti

Authors
  1. Jan F. Rabek
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  2. Julia Lucki
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  3. Henryk Kereszti
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Rabek, J.F., Lucki, J. & Kereszti, H. Forced crystallization of poly(1,5-di-oxapene-2-one)-Fe(III) chloride complex onto NaCl surface by polymerizing pyrrole. Polymer Bulletin 24, 529–532 (1990). https://doi.org/10.1007/BF00395575

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  • DOI: https://doi.org/10.1007/BF00395575

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