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Living cationic polymerization of isobutyl vinyl ether, 2

Telechelics by controlled chain termination and their application to the synthesis of blockcopolymers

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Summary

Living cationic polymerization of isobutul vinyl ether (IBVE), initiated by1-iodo-1-(2-methyl propyloxy)-ethane (1) and tetraalkylammonium perchlorate yields polymers of well defined molar masses and end groups. The controlled introduction of end groups was confirmed by a model reaction and was then applied to introduce and azo initiator function. The resulting polymeric initiator was used for the synthesis of a blockcopolymer.

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Authors and Affiliations

  1. Lehrstuhl für Makromolekulare Chemie I, Universität Bayreuth, W-8580, Bayreuth, Federal Republic of Gerymany

    Oskar Nuyken, Hubertus Kröner & Stefan Aechtner

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  1. Oskar Nuyken
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  2. Hubertus Kröner
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  3. Stefan Aechtner
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Nuyken, O., Kröner, H. & Aechtner, S. Living cationic polymerization of isobutyl vinyl ether, 2. Polymer Bulletin 24, 513–519 (1990). https://doi.org/10.1007/BF00395573

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