Abstract
Coarse grained garnet-pyroxene coronas in anorthositic gabbros of the Bergen and Sognefjord areas preserve relics of two stages of reaction during cooling from magmatic T: (1) ol + plag→cpx I+ opxI + spn; (2) cpxI + opxI + spn + plag→cpxII + opxII + gnt.
Geothermobarometry on the products of reaction (1), using Fe3+ cpx and AlIV opx values derived by X-ray structure refinement (XRef), yields T=900–950° C, P=10–11 kb. Even higher T, probably at lower P, is inferred for reaction (2); this is consistent with TEM observations of pigeonite lamellae in cpxI.
Transmission electron microscopy (TEM) observations show abundant submicroscopic amphibole lamellae in cpxII, and XRef analyses of coexisting massive amphiboles suggest incomplete occupancy of the H site; both observations suggest low but finite \(p_{H_2 O}\) during granulite-facies metamorphism. TEM observations also show that later (retrograde) hydration, particularly of orthopyroxenes, is more extensive than suggested by petrographic studies. Late amphiboles have fully occupied H sites, indicating higher \(p_{H_2 O}\). The integration of XRef and TEM studies with more conventional petrographic and electron microprobe (EMP) data, as in this study, gives a powerful tool for the study of metamorphic reactions.
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References
Austrheim H, Griffin WL (1985) Shear deformation and eclogite formation within granulite-facies anorthosites in the Bergen Arcs, western Norway. Chem Geol (in press)
Austrheim H, Robins B (1981) Reaction involving hydration of orthopyroxene in anorthosite-gabbro. Lithos 14:275–281
Burnham CW, Ohashi Y, Hafner SS, Virgo D (1971) Cation distribution and atomic thermal vibrations in an iron-rich orthopy-roxene. Am Mineral 56:850–876
Buseck PR, Veblen DR (1978) Trace elements, crystal defects and high resolution electron microscopy. Geochim Cosmochim Acta 42:669–672
Buseck PR, Nord GL Jr, Veblen DR (1980) Subsolidus phenomena in pyroxenes. In: Prewitt CT (ed) Reviews in Mineralogy, vol. 7, Pyroxenes. Mineralogical Society of America, Washington DC
Cameron M, Sueno S, Prewitt CT, Papike JJ (1973) High-temperature crystal-chemistry of acmite, diopside, hedenbergite, Jadeite, spodumene and ureyite. Am Mineral 58:594–618
Carswell DA, Griffin WL (1981) Calculation of equilibration conditions for garnet granulite and garnet websterite nodules in African kimberlite pipes. Tschermaks Mineral Petrogr Mitt 28:229–244
Clark JR, Appleman DE, Papike JJ (1969) Crystal-chemical characterization of clinopyroxenes based on eight new structure refinements. Mineral Soc Am Spec Pap 2:31–50
Dal Negro A, Carbonin S, Molin GM, Cundari A, Piccirillo EM (1982) Intracrystalline cation distribution in natural clinopyroxenes of tholeitic, transitional and alkaline basaltic rocks. In: Saxena SK (ed) Advances in physical geochemistry, vol. 2. Springer, Berlin Heidelberg New York, pp 117–150
Desnoyers C (1975) Exsolution d'amphiboles, de granat et de spinelle dans le pyroxenes de roches ultrabasiques: peridotites et pyroxenolites. Bull Mineral 98:65–77
Ellis DJ, Green DH (1979) An experimental study of the effect of Ca upon garnet-clinopyroxene Fe-Mg exchange equilibrium. Contrib Mineral Petrol 71:13–22
Ganguly J, Ghose S (1979) Aluminous orthopyroxenes: order-disorder, thermodinamic properties and petrological implications. Contrib Mineral Petrol 66:375–385
Gasparik T (1984) Two-pyroxene thermobarometry with new experimental data in the system CaO-MgO-Al2O3-SiO2. Contrib Mineral Petrol 87:87–97
Ghose S, Wan C (1973) Luna 20 pyroxenes: evidence for a complex thermal history. Proceedings of the 4th Lunar Science Conference 1:901–907
Griffin WL (1971) Genesis of coronas in anorthosites of the Upper Jotun Nappe, Indre Sogn, Norway. J Petrol 12:219–243
Griffin WL (1972) Formation of eclogites and the coronas in anorthosites, Bergen Arcs, Norway. Geol Soc Am Mem 135:37–63
Griffin WL, Heier KS (1973) Petrological implications of some corona structures. Lithos 6:315–335
Griffin WL, Carswell DA, Nixon PH (1979) Lower-crustal granulites and eclogites from Lesotho, Southern Africa. In: Boyd FR, Meyer HOA (ed) The Mantle Sample: Inclusions in kimberlites and other volcanics. Proceedings of the Second Kimberlite Conference vol 2. Am Geophys Union, Washington DC
Griffin WL, Wass SY, Hollis JD (1984) Ultramafic xenoliths from Bullenmerri and Gnotuk maars, Victoria, Australia: Petrology of a sub-continental crust-mantle transition. J Petrol 25:53–87
Griffin WL, Austrheim H, Brastad K, Bryhni I, Krill AG, Krogh EJ, Mork MBE, Quale H, Torudbakken B (1985) High-pressure metamorphism in the Scandinavian Caledonides. In: Gee DG, Sturt BA (ed) The Caledonide orogen. Wiley (in press)
Harley SL, Green DH (1982) Garnet-orthopyroxene barometry for granulites and peridotites. Nature 300:697–701
Herzberg CT (1978) Pyroxene geothermometry and geobarometry: experimental and thermodynamic evaluation of some subsolidus relations involving clinopyroxenes in the system CaO-MgO-Al2O3-SiO2. Geochim Cosmochim Acta 42:945–957
Huebner JS (1980) Pyroxene phase equilibria at low pressure. In: Prewitt CT (ed) Reviews in Mineralogy, 7, Pyroxenes, Mineralogical Society of America. Washington DC, pp 213–288
Jaffe HW, Robinson P, Tracy RJ, Ross M (1975) Orientation of pigeonite exsolution lamellae in metamorphic augite: correlation with composition and calculated optimal phase boundaries. Am Mineral 60:9–28
Kay S, Kay R (1983) Thermal history of the deep crust inferred from granulite xenoliths, Queensland, Australia. Am J Sci 283 A:486–513
Koestler AG (1982) A Precambrian age for the Ofredal granodiorite intrusion, central Jotun Nappe, Sogn, Norway. Norsk Geol Tidsskr 62:225–228
Kosoi AL, Malkova LA, Frank-Kamenetsi VA (1974) Crystal-chemical characteristics of rhombic pyroxenes. Kristallografiya 19:282–288 (transl. Soviet Physics and Crystallography 19:171–174
Lindsley DH (1980) Phase equilibria of pyroxenes at pressures >1 atmosphere. In: Prewitt CT (ed) Reviews in Mineralogy 7, Pyroxenes, Mineralogical Society of America, Washington DC, pp 289–307
Mellini M, Oberti R, Rossi G (1983) Crystal-chemistry and microstructures of pyroxenes and amphiboles in the coronas of the Bergen Arcs and of the Sognefjord region, Western Norway. Period Mineral 52:583–615
Oliver GJH (1977) Feldspathic hornblende and garnet granulites and associated anorthosite pegmatites from Doubtful Sound, Fiordland, New Zealand. Contrib Mineral Petrol 65:111–121
Ramberg H (1981) Gravity, deformation and the earth's crust. Academic Press, London, 452 pp
Rossi G, Tazzoli V, Ungaretti L (1981) Crystal-chemical studies on sodic clinopyroxenes. Proceedings of the XI General Meeting of I.M.A., Rock — forming minerals, pp 20–45
Rossi G, Smith DC, Ungaretti L, Domeneghetti MC (1983a) Crystal-chemistry and cation ordering in the system diopside-jadeite: a detailed study by crystal structure refinement. Contrib Mineral Petrol 83:247–258
Rossi G, Smith DC, Ungaretti L, Domeneghetti MC (1983b) Comparison of chemical analyses of sodic pyroxenes by X-ray structure refinement and electron microprobe techniques. Period Mineral 52:343–354
Saxena SK, Ghose S (1971) Mg2+-Fe2+ order-disorder and the thermodynamics of the orthopyroxene crystalline solution. Am Mineral 56:532–559
Smith PPK (1977) An electron microscopic study of amphibole lamellae in augite. Contrib Mineral Petrol 83:247–258
Ungaretti L (1980) Recent developments in X-ray single crystal diffractometry applied to the crystal-chemical study of amphiboles. God Jugosl Cent Kristalogr 15:29–65
Ungaretti L, Smith DC, Rossi G (1981) Crystal-chemistry by X-ray structure refinement and electron microprobe analysis of a series of sodic-calcic to alkali amphiboles from the Nybö eclogite pod, Norway. Bull Mineral 104:400–412
Ungaretti L, Lombardo B, Domeneghetti MC, Rossi G (1983) Crystal-chemical evolution of amphiboles from eclogitised rocks of the Sesia-Lanzo zone, Italian western alps. Bull Mineral 106:645–672
Veblen R, Buseck PR (1981) Hydrous pyriboles and sheet silicates in pyroxenes and urolithes: intergrowth microstructures and reaction mechanism. Am Mineral 66:1107–1134
Virgo D, Hafner S (1969) Fe2+, Mg order in heated orthopyroxenes. Mineral Soc Spec Pap 2:67–81
Yamaguchi Y, Akai J, Tomita K (1978) Clinoamphibole lamellae in diopside of garnet lherzolite from Alpe Arami, Bellinzona, Switzerland. Contrib Mineral Petrol 66:263–270
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Griffin, W.L., Meillini, M., Oberti, R. et al. Evolution of coronas in Norwegian anorthosites: re-evaluation based on crystal-chemistry and microstructures. Contr. Mineral. and Petrol. 91, 330–339 (1985). https://doi.org/10.1007/BF00374689
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DOI: https://doi.org/10.1007/BF00374689