Skip to main content
Log in

High temperature alteration of Abyssal ultramafics from the Islas Orcadas Fracture Zone, South Atlantic

  • Published:
Contributions to Mineralogy and Petrology Aims and scope Submit manuscript

Abstract

Ultramafic rocks dredged from the Islas Orcadas Fracture Zone, along the SW Indian Ocean Ridge (6° E and 54° S), show evidence of progressive hydration beginning at temperatures greater than 600° C (and perhaps as high as 900° C) and continuing to less than 50° C. There are two principal types of alteration present in the ultramafic rocks, both of which are the result of hydration reactions. The first type of alteration involves hydration of original clinopyroxene, orthopyroxene and olivine to amphibole, talc, secondary olivine, and serpentine. The second is a vein type of alteration and results in the formation of veins of amphibole, chlorite, talc and serpentine. — The alteration appears to be episodic. The sequence of events suggested by the petrography is: 1) clinopyroxene altering to amphibole; 2) orthopyroxene altering to talc, or talc + olivine; 3) supersolvus hornblende veining; 4) coexisting actinolite + hornblende veining; 5) chlorite, chlorite + actinolite, or chlorite + secondary clinopyroxene veining; 6) talc veining; 7) serpentine veining; and 8) pervasive serpentinization. — The alteration fluid is most likely seawater. It is suggested that the high temperature alterations may reflect seawater circulation into the upper mantle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Aumento F, Loubat H (1971) The Mid-Atlantic Ridge near 45° N XVI. Serpentinized ultramafic intrusions. Can J Earth Sci 8:631–663

    Google Scholar 

  • Bonatti E (1976) Serpentine protrusions in the oceanic crust. Geol Soc Am Bull 507–530

  • Brady JB (1974) Coexisting actinolite and hornblende from west-central New Hampshire. Am Mineral 59:529–535

    Google Scholar 

  • Burnham CW, Holloway JR, Davis NF (1969) Thermodynamic properties of Water to 1,000° C and 10,000 bars. Geol Soc Am Special Pap 132:96

    Google Scholar 

  • Choudhuri A (1974) Distribution of Fe and Mg in some Precambrian metagreywackes from Guyana South America. Contrib Mineral Petrol 44:45–55

    Google Scholar 

  • Cooper AF, Lovering JF (1970) Greenschist amphiboles from Haast River, New Zealand. Contrib Mineral Petrol 27:11–24

    Google Scholar 

  • Crowley P, Spear FS (1981) The orthoamphibole solvus: P, T, X (Fe-Mg) relations. GSA Abs Prog 13:435

    Google Scholar 

  • Dick HJB (1979) Alteration and metamorphism of peridotite at Islas Orcadas Fracture Zone (abstr) EOS Trans. Am Geophys Un 60:973

    Google Scholar 

  • Dick HJB, Fisher RL, Bryan WB (1984) Mineralogic variability of the uppermost mantle along mid-ocean ridges. Earth Planet Sci Lett 69:58–106

    Google Scholar 

  • Dick HJB, Bullen T (1984) Chromian spinel as a petrogenetic indicator in abyssal and alpine-type peridotites and spatially associated lavas. Contrib Mineral Petrol 86:54–76

    Google Scholar 

  • Fawcett JJ, Yoder HS Jr (1966) Phase relations of chlorites in the system MgO-Al2O3-SiO2-H2O. Am Mineral 51:353–380

    Google Scholar 

  • Ferry JM (1983) Applications of the reaction progress variable in metamorphic petrology. J Petrol 24:343–376

    Google Scholar 

  • Fox PJ, Detrick RS, Purdy GM (1980) Evidence for crustal thinning near fracture zones: Implications for ophiolites. In: Panayioutu A (ed) Ophiolites: Proceedings of the International Ophiolite Symposium. Geol Survey of Cyprus, Nicosia, pp 161–168

    Google Scholar 

  • Francheteau J, Choukroune P, Hekinian R, LePichon X, Needham D (1976) Oceanic Fracture zones do not provide deep sections into the crust. Can J Earth Sci 13:1223–1235

    Google Scholar 

  • Graham CM (1974) Metabasite amphiboles of the Scottish Dalradian. Contrib Mineral Petrol 47:165–185

    Google Scholar 

  • Grapes RH, Graham CM (1978) The actinolite-hornblende series in metabasites and the so-called miscibility gap: a review. Lithos 11:85–97

    Google Scholar 

  • Harper GD (1985) Tectonics of slow spreading mid-ocean ridges and consequences of a variable depth to the brittle/ductile transition. Tectonics 4:395–409

    Google Scholar 

  • Harte B, Graham CM (1975) The graphical analysis of greenschist to amphibolite facies mineral assemblages in metabasites. J Petrol 16:347–370

    Google Scholar 

  • Helgeson HC, Delany JM, Nesbitt HW, Bird DK (1978) Summary and critique of the thermodynamic properties of rock forming minerals. Am J Sci 278-A:1–229

    Google Scholar 

  • Hemley JJ, Montoya JW, Christ CL, Hostetler PB (1977a) Mineral equilibria in the MgO-SiO2-H2O system: I. Talc-chrysotile-forsterite-brucite stability relations. Am J Sci 277:322–335

    Google Scholar 

  • Hemley JJ, Montoya JW, Shaw DR, Luce RW (1977b) Mineral equilibria in the MgO-SiO2-H2O system: II. Talc-antigorite-forsterite-anthophyllite-enstatite stability relations and some geologic implications in the system. Am J Sci 277:353–383

    Google Scholar 

  • Janecky DR (1982) Serpentinization of peridotite within the oceanic crust: experimental and theoretical investigations of seawater-peridotite interaction at 200° C and 300° C 500 bars. PhD Diss, Univ of Minnesota

  • Johannes W (1968) An experimental investigation of the system MgO-SiO2-H2O-CO2. Am J Sci 267:1083–1104

    Google Scholar 

  • Kimball KL, Spear FS (1984) Compositional constraints on hydrothermal alteration fluids; Islas Orcadas Fracture Zone. EOS 65:228

    Google Scholar 

  • Kimball KL, Gerlach DC, Spear FS (1984) Calculated models of Mg-Fe-SiO2-Cl-H2O fluid evolution and valuable 87Sr/86Sr in alteration veins from Islas Orcadas Fracture Zone ultramacis. EOS 65:1124

    Google Scholar 

  • Kitahara S, Kennedy GC (1967) The calculated equilibrium curves for some reactions in the system MgO-SiO2-H2O at pressures up to 30 kilobars. Am J Sci 265:211–217

    Google Scholar 

  • Kitahara S, Takenochi S, Kennedy GC (1966) Phase relations in the system MgO-SiO2-H2O at high pressures. Am J Sci 264:223–233

    Google Scholar 

  • Klein C (1969) Two-amphibole assemblages in the system actinolite-hornblende-glaucophane. Am Mineral 54:212–237

    Google Scholar 

  • Kretz R, Jen LS (1978) Effect of temperature on the distribution of Mg and Fe between calcic pyroxene and hornblende. Can Mineral 16:533–537

    Google Scholar 

  • Liou JG, Kuniyoshi S, Ito K (1974) Experimental studies of the phase relations between green schist and amphibolite in a basaltic system. Am J Sci 274:613–632

    Google Scholar 

  • Leake BE (1978) Nomenclature of amphiboles. Can Mineral 16:501–520

    Google Scholar 

  • Misch P, Rice JM (1975) Miscibility of tremolite and hornblende in progressive Skagit Metamorphic Suite, North Cascades, Washington. J Petrol 16:1–21

    Google Scholar 

  • Mottl MJ (1983) Metabasalts, axial hotsprings, and the structure of hydrothermal systems at mid-ocean ridges. Geol Soc Am Bull 94:161–180

    Google Scholar 

  • Oba T (1980) Phase relations in the tremolite-pargasite join. Contrib Mineral Petrol 71:247–256

    Google Scholar 

  • OTTER (1983) The geology of the oceanographer transform: the ridge-transform intersection. Mar Geophys Res 6:109–141

    Google Scholar 

  • Ragnarsdottir KV, Walther JV, Arnorsson S (1984) Description and interpretation of the composition of fluid and alteration mineralogy in the geothermal system at Svartsengi, Iceland. Geochim Cosmochim Acta 48:1535–1553

    Google Scholar 

  • Reed MH (1982) Calculation of multicomponent chemical equilibria and reaction processes in systems involving minerals, gases and an aqueous phase. Geochim Cosmochim Acta 46:513–528

    Google Scholar 

  • Reed MH (1983) Seawater-basalt reaction and the origin of greenstones and related ore deposits. Econ Geol 78:466–485

    Google Scholar 

  • Robinson P, Spear FS, Schumaker JC, Laird J, Klein C, Evans BW, Doolan BW (1981) Phase relations of metamorphic amphiboles: natural occurrence and theory. In: Veblen D (ed) Amphiboles and other hydrous pyriboles-Mineralogy, MSA Rev Mineral 9B

  • Sampson GA, Fawcett JJ (1977) Coexisting amphiboles from the Hastings region of southeastern Ontario. Can Mineral 15:283–296

    Google Scholar 

  • Schulien S, Friedricksen H, Hellner E (1970) Das Mischkristallverhalten des Olivins zwischen 450° C and 650° C bei 1 Kb Druck, N Jahrb Mineral Monath, pp 141–147

  • Sleep NH (1975) Formation of oceanic crust: Some thermal constraints. J Geophys Res 80:4037–4042

    Google Scholar 

  • Spear FS (1976) Phase equilibria and mineral chemistry of a hydrothermally-synthesized amphibolite. PhD Diss, UCLA

  • Spear FS (1981) An experimental study of hornblende stability and compositional variability in amphibolite. Am J Sci 281:697–734

    Google Scholar 

  • Stroup J, Fox P (1981) Geologic investigations in the Cayman Trough Evidence for thin oceanic crust along the Mid-Cayman Rise. J Geol 89:395–420

    Google Scholar 

  • Tagiri M (1977) Fe-Mg partition and miscibility gap between coexisting calcic amphiboles from the Southern Abukuma Plateau Japan. Contrib Mineral Petrol 62:271–281

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kimball, K.L., Spear, F.S. & Dick, H.J.B. High temperature alteration of Abyssal ultramafics from the Islas Orcadas Fracture Zone, South Atlantic. Contr. Mineral. and Petrol. 91, 307–320 (1985). https://doi.org/10.1007/BF00374687

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00374687

Keywords

Navigation