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Retrogressive development of glaucophane in some eclogites from “Massif Armoricain” (East of Nantes, France)

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Abstract

A petrological and mineralogical study, using an electron microprobe, of a blue-amphibole eclogite occurring near Nantes (Massif Armoricain, France) has enabled us to characterize this amphibole as glaucophane resulting from a secondary reaction in the rock. This sodic amphibole was formed at the expense of primary eclogite paragenesis including omphacite, garnet and quartz, according to a sliding reaction which it was possible to study quantitatively: 3.24 omphacite+0.90 SiO2+0.76 garnet+1.08 H2O =1 glaucophane+0.55 grossular (S.S. in the garnet) +0.04 paragonite.

This reaction is accompanied by a variation in the distribution of iron and magnesium between the amphibole, the garnet and the omphacite.

The appearance of the glaucophane can be explained as the beginning of a retromorphic evolution from the stable physical conditions of the primary eclogite paragenesis (650±100° C; minimum pressure 15 Kb).

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References

  • Anthonioz PM, Brillanceau A (1969) Introduction à la géologie de la région de Bois-de-Cené (Vendée): un nouveau jalon du métamorphisme de haute-pression dans le Massif Armoricain. CR Acad Sci Paris T 269, série D: 1050–1052

  • Brière Y (1920) Les éclogites françaises, leur composition et leur origine. Bull Soc Fr Mineral T 43:77–222

    Google Scholar 

  • Carlier G (1978) Etude des associations réactionnelles à structures coronitiques dans les métagabbros de la région nantaise. Thèse 3ème cycle, Paris VI

  • Cogné J (1966) Une “nappe” cadomienne de style pennique: la série cristallophyllienne de Champtoceaux en bordure méridionale du synclinal d'Ancenis (Bretagne-Anjou). Bull Serv Carte Geol Als Lorr 19–2:107–136

    Google Scholar 

  • Currie KL, Curtis LW (1976) An application of multicomponent solution theory to jadeitic pyroxenes. J Geol, USA 84 (n° 2):179–194

    Google Scholar 

  • Ellis DJ, Green DH (1979) An experimental study of the effect of Ca upon Garnet-Clinopyroxene Fe-Mg exchange equilibria. Contrib Mineral Petrol 71:13–22

    Google Scholar 

  • Essene EJ, Fyfe WS (1967) Omphacite in Californian metamorphic rocks. Contrib Mineral Petrol 15:1–23

    Google Scholar 

  • Ganguly J (1979) Garnet and clinopyroxene solid solutions, and geothermometry based on Fe-Mg distribution coefficient. Geochim Cosmochim Acta 43:1021–1029

    Google Scholar 

  • Hensen BJ (1971) Theoretical Phase relations involving cordierite and garnet in the system MgO-FeO-Al2O3-SiO2. Contrib Mineral Petrol 33:191–214

    Google Scholar 

  • Hoffmann C (1972) Natural and synthetic ferro-glaucophane. Contrib Mineral Petrol 34:135–149

    Google Scholar 

  • Holland TJB (1979) High water activities in the generation of high pressure kyanite eclogites of the Tauern window, Austria. J Geol 87:1–27

    Google Scholar 

  • Johannes W, Bell PM, Mao HK, Boettcher AL, Chipman OW, Hayes JF, Newton RC, Seifert F (1971) An interlaboratory comparison of piston-cylinder pressure calibration using the albite breakdown reaction. Contrib Mineral Petrol 32:24–28

    Google Scholar 

  • Kienast JR, Triboulet C (1972) Le chloritoïde dans les paragenèses à glaucophane, albite ou paragonite. Bull Soc Fr Mineral Cristallogr 95:565–573

    Google Scholar 

  • Krogh EJ, Råheim A (1978) Temperature and pressure dependance of Fe-Mg partitioning between garnet and phengite, with particular reference to eclogites. Contrib Mineral Petrol 66:75–80

    Google Scholar 

  • Kushiro I (1969) Clinopyroxene solid solutions formed by reactions between diopside and plagioclase at high pressures. Mineral Soc Am Spec Pap 2:179–191

    Google Scholar 

  • Lacroix A (1891) Etude pétrographique des éclogites de la Loire-Inférieure. Bull Soc Sciences Naturelles de l'Ouest de la France I:81–114

    Google Scholar 

  • Lappin MA, Smith DC (1978) Mantle-equilibrated Orthopyroxene Eclogite Pods from the Basal Gneisses in the Selje District, Western Norway. J Petrol 19:530–584

    Google Scholar 

  • Lasnier B (1970) Le métamorphisme régional des gabbros d'après la littérature internationale. Etude préliminaire des gabbros coronitiques du Massif Armoricain et du Massif des Maures, France. Thèse 3ème cycle, Nantes, 297 p

  • Lasnier B, Leyreloup A, Marchand J (1973) Découverte d'un granite “charnockitique” au sein de “gneiss oeillés”. Perspectives nouvelles sur l'origine de certaines leptynites du Massif Armoricain méridional (France). Contrib Mineral Petrol 41:131–144

    Google Scholar 

  • Leake BE (1978) Nomenclature of amphiboles. Am Mineral 63:1023–1052

    Google Scholar 

  • Liebaux C (1975) Caractères généraux des roches du faciès éclogitique de la zone de Sesia-Lanzo (Alpes italiennes). Thèse 3ème cycle, Paris VI

  • Maresch WV (1977) Experimental studies on glaucophane: an analysis of present knowledge. Tectonophysics 43:109–125

    Google Scholar 

  • Papike JJ, Cameron KL, Baldwin K (1974) Amphiboles and pyroxenes: characterization of other than quadrilateral components and estimates of ferric iron from microprobe data. Geol Soc Am Abstr Progr 6:1053–1054

    Google Scholar 

  • Peucat JJ, Vidal Ph, Godard G, Postaire B 1.25–1.34 B.Y. old oceanic crust in the W. European hercynian belt? Precambrian U-Pb zircon ages from eclogite and garnet pyroxenite from south Brittany (France). Earth Planet Sci Lett (submitted in 1981)

  • Råheim A, Green DH (1975) P, T paths of natural eclogites during metamorphism — a record of subduction. Lithos 8:317–328

    Google Scholar 

  • Reinsch D (1979) Glaucophanites and eclogites from Val Chiusella, Sesia-Lanzo zone (Italian Alps). Contrib Mineral Petrol 70:257–266

    Google Scholar 

  • Robie RA, Bethke PM, Toulmin MS, Edwards JL (1966) X-ray crystallographic data, densities and molar volumes of minerals. In Handbook of Physical Constants. Geol Soc Am Mem 97:70

    Google Scholar 

  • Robie RA, Hemingway BS, Fisher JR (1979) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and high temperatures. Geol Surv Bull: 1452

  • Saxena SK (1979) Garnet-clinopyroxene geothermometer. Contrib Mineral Petrol 70:229–235

    Google Scholar 

  • Smith DC (1971) A tourmaline-bearing eclogite from Sunnmöre, Norway. Norsk Geol Midss 51:141–147

    Google Scholar 

  • Smith DC (1980) Exceptional mineral compositions in very high pressure hydrous-eclogite-facies parageneses in the Precambrian suite of eclogite lenses in the Selje and Vartdalsfjorden Districts of the Basal Gneiss Region, SW Norway. 26th Int Geol Congr Paris (Abstr), p 92

  • Velde B (1966) Etude minéralogique d'une éclogite de Fay-de-Bretagne. Bull Soc Fr Mineral Cristallogr LXXXIX:385–393

    Google Scholar 

  • Velde B (1970) Les éclogites de la région nantaise (de Campbon au Cellier, Loire-Atlantique). Bull Soc Fr Mineral Cristallogr 93:370–385

    Google Scholar 

  • Vidal Ph, Peucat JJ, Lasnier B (1980) Dating of granulites involved in the Hercynian Fold-Belt of Europe: An example taken from the granulite-facies orthogneisses at La Picherais, Southern Armoricain Massif, France. Contrib Mineral Petrol 72:283–289

    Google Scholar 

  • Zen EA (1974) Prehnite and Pumpellyite — bearing mineral assemblages, west side of the appalachian metamorphic belt, Pennsylvania to Newfoundland. J Petrol 15:197–242

    Google Scholar 

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Godard, G., Kienast, J.R. & Lasnier, B. Retrogressive development of glaucophane in some eclogites from “Massif Armoricain” (East of Nantes, France). Contr. Mineral. and Petrol. 78, 126–135 (1981). https://doi.org/10.1007/BF00373774

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