Abstract
A detailed study of the phase chemistry of selected lavas from Vico shows that the “excess silica” in leucite is a significant and widespread crystal-chemical characteristic which may be interpreted in terms of an extended solubility of KAlSi3O8 and/or differential loss of potassium from the leucite structure. Plagioclase geothermometer data suggest increasing plagioclase control in the differentiation with decreasing Mg/Mg+Fe2+ ratios for the bulk rocks. The pyroxene compositions show moderate amounts of ferri-Tschermak's and Ca-Tschermak's molecules, probably controlled by temperature and compositional variations in the cooling liquids. Both microphenocrystal and late-crystallizing micas correspond to phlogopite compositions throughout the suite.
The phase chemistry is discussed in relation to the differentiation of the suite and current petrogenetic models.
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Cundari, A. Mineral chemistry and petrogenetic aspects of the Vico lavas, Roman volcanic region, Italy. Contr. Mineral. and Petrol. 53, 129–144 (1975). https://doi.org/10.1007/BF00373127
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DOI: https://doi.org/10.1007/BF00373127