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Uranium and microcracks in a 1,000-meter core, Redstone, New Hampshire

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Abstract

The spatial distribution and mineralogical association of uranium in 30 samples of a 1,000 meter core from the Redstone (NH) Quarry were examined with fission track techniques, backscattered electron imaging, and energy dispersive X-ray spectrometry with the following results for the Conway and Mount Osceola granites: (1) Uranium occurs in microcracks sealed with siderite and/or with Ca+ RE fluorocarbonate minerals; the uranium contents of siderite and the RE fluorocarbonates are 1 to 30 ppm and 500–1,500 ppm, respectively. (2) Siderite and to a lesser extent RE fluorocarbonate minerals occur as replacement minerals of amphibole and biotite; the RE fluorocarbonates are the main alteration minerals of allanite. (3) The degree of alteration and the extent of uranium redistribution are greater in samples with major uraniferous microcracks. (4) The contents of Ca and Mn are approximately constant for siderite in sealed cracks throughout the Conway and Mount Osceola granites for the entire section penetrated by the corehole, approximately 700 meters. — From these observations, we conclude that an extensive set of fractures throughout a significant volume of the Mount Osceola and Conway granties were the conduits through which hydrothermal fluids containing CO2, uranium, and REs circulated. Microcracks facilitated fluid-rock interactions resulting in alteration and uranium redistribution. Certain primary uraniferous accessory minerals, i.e., allanite and ilmenorutile may have been the source for at least part of the uranium and REs that now occur in secondary minerals in these granites.

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References

  • Alderton DHM, Pearce JA, Potts PJ (1980) Rare earth mobility during granite alteration: evidence from southwest England. Earth Planet Sci Lett 49:149–165

    Google Scholar 

  • Amiel S (1962) Analytical applications of delayed neutron emission in fissionable elements. Anal Chem 34:1683–1692

    Google Scholar 

  • Bandurkin GA (1961) Behavior of the rare earths in fluorine-bearing media. Geochemistry 159–167

  • Billings MP (1956) The geology of New Hamsphire, Part II: Bedrock Geology, New Hamsphire Plan. Devel Comm.: 203 pp

  • Billings MP, Keevil NB (1946) Petrography and radioactivity of four Paleozoic magma series in New Hamsphire. Bull Geol Soc Am 57:797–828

    Google Scholar 

  • Brimhall WH, Adams JAS (1969) Concentration changes of thorium, uranium, and other metals in hydrothermally altered Conway granite, New Hamsphire. Geochim Cosmochim Acta 33:1308–1311

    Google Scholar 

  • Butler AP, Jr (1961) Ratio of thorium to uranium in some plutonic rocks of the White Mountain plutonic-volcanic series, New Hampshire, USGS Prof Paper 424-B:67–69

    Google Scholar 

  • Caruso L, Simmons G (1981) Uranium and REE migration in the Sherman granite, SE Wyoming. EOS 62:1064

    Google Scholar 

  • Caruso L, Swinden T, Simmons G (1982) Uranium migration through microcracks, Geevor Tin Min, Cornwall, England. EOS 63:1128

    Google Scholar 

  • Caruso L, Simmons G (1984a) The distribution of U in the Sherman granite, SE Wyoming: Implications on U mobility (in preparation)

  • Caruso L, Simmons G (1984b) Geological applications of backscattered electron imaging. In: Electron Microscopy in Geology, Proceedings Volume, (in press)

  • Clark AM (1984) Mineralogy of the rare earth elements. In Henderson P (editor) Rare Earth Geochemistry 33–61

  • Creasy JW (1974) Mineralogy and petrology of the White Mountain batholith, Franconia and Crawford Notch quadrangles, New Hamsphire. PhD thesis, Harvard University

  • Cuny M (1978) Geologic environment, mineralogy, and fluid inclusions of the Bois Noirs-Limouzat uranium vein, Forez, France. Econ Geol 73:1567–1610

    Google Scholar 

  • Deer WA, Howie RA, Zussman J (1962) Rock-forming minerals. 1:211–220

    Google Scholar 

  • Derry DR (1973) Ore deposition and contemporaneous surfaces. Econ Geol 68:1374–1380

    Google Scholar 

  • Fehn U, Cathles LM, Holland HD (1978) Hydrothermal convection and uranium deposits in abnormally radioactive plutons. Econ Geol 73:1556–1566

    Google Scholar 

  • Fleischer M (1978) Relative proportions of the lanthanides in the minerals of the bastnaesite group. Can Mineral 16:361–363

    Google Scholar 

  • Fleischer RL, Price PB, Walker RM (1975) Nuclear Tracks in Solids: Principles and Applications, University of California Press, Berkeley 605 pp

    Google Scholar 

  • Foland KA, Faul H (1977) Ages of the White Mountain intrusives — New Hampshire, Vermont, and Maine, USA. Am J Sci 277:888–904

    Google Scholar 

  • Garrels RM, Christ CL (1965) Solutions, Minerals, and Equilibria, Freeman, Cooper&Company, San Francisco

    Google Scholar 

  • Hoag RB Jr, Stewart GW (1977) Preliminary petrographic and geophysical interpretations of the exploratory geothermal drill hole and core, Redstone, New Hamsphire. Report prepared for ERDA under contract no. EY-76-S-02-2720

  • Hoisington WD (1977) Uranium and thorium distribution in the Conway granite of the White Mountain batholith. Ms thesis, Dartmouth College

  • Hostetler PB, Garrels RM (1962) Transportation and precipitation of uranium and vanadium at low temperatures, with special reference to sandstone-type uranium deposits. Econ Geol 57:137–167

    Google Scholar 

  • Jaupart C, Mann JR, Simmons G (1982) A detailed study of the distribution of heat flow and radioactivity in New Hamsphire (USA). Earth Planet Sci Lett 59:267–287

    Google Scholar 

  • Kosterin AV (1959) The possible modes of transport of the rare earths by hydrothermal solutions. Geochemistry 381–387

  • Langford FF (1974) A supergene origin for vein-type uranium ores in the light of the western Australian calcrete-carnotite deposits. Econ Geol 69:516–526

    Google Scholar 

  • Langmuir D (1978) Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits. Geochim Cosmochim Acta 42:547–569

    Google Scholar 

  • Leroy J (1978) The Margnac and Fanay uranium deposits of the La Crouzille district (western Massif Central, France): geologic and fluid inclusion studies. Econ Geol 73:1611–1634

    Google Scholar 

  • Ludwig KR, Nash JT, Naeser CW (1981) U-Pb isotope systematics and age of uranium mineralization, Midnite Mine, Washington. Econ Geol 76:89–110

    Google Scholar 

  • Ludwig KR, Stuckless JS (1978) U-Pb isotope systematics and apparent ages of zircon and other minerals in PE granitic rocks, Granite Mountains, Wyoming. Contrib Mineral Petrol 65:243–254

    Google Scholar 

  • Maurice YT (ed) (1982) Uranium in Granites, Canada Geological Survey Paper 81–23

  • Millard HT Jr (1976) Determination of uranium and thorium in USGS standard rocks by the delayed neutron technique. USGS Prof Paper 840:61–65

    Google Scholar 

  • Neuerberg GJ (1955) Uranium in igneous rocks of the United States. USGS Prof Paper 300:55–64

    Google Scholar 

  • Norton D, Knapp R (1977) Transport phenomena in hydrothermal systems: the nature of porosity. Am J Sci 277:913–936

    Google Scholar 

  • Norton D, Knight J (1977) Transport phenomena in hydrothermal systems: cooling plutons. Am J Sci 277:937–981

    Google Scholar 

  • Osberg PH, Wetterauer R, Rivers M, Bothner WA, Creasy JW (1978) Feasibility study of the Conway granite as a geothermal energy resource. Report prepared for ERDA under contract no. EY-76-5-02-2686

  • Rich RA, Holland HD, Petersen U (1977) Hydrothermal Uranium Deposits. Elvevier, Amsterdam

    Google Scholar 

  • Richardson KA (1964) Thorium, uranium, and potassium in the Conway granite, New Hampshire, USA. In: The Natural Radiation Environment, University of Chicago Press, Chicago, pp 39–50

    Google Scholar 

  • Richter D, Simmons G (1977) Microcracks in crustal igneous rocks: Microscopy. In: Heacock J (ed) The Earth's Crust, American Geophysical Union, Washington, DC pp 149–180

    Google Scholar 

  • Robinson VNE (1975) Backscattered electron imaging. Proc Ann Scanning Electron Microscope Symposium, pp 51–57

  • Rogers JJW, Adams JAS (1963) Log normality of thorium concentrations in the Conway granite. Geochim Cosmochim Acta 27:775–783

    Google Scholar 

  • Rogers JJW, Adams JAS, Gatlin B (1965) Distribution of thorium, uranium, and potassium concentrations in three cores from the Conway granite, New Hampshire, USA Am J Sci 263:817–822

    Google Scholar 

  • Rogers JJW, Ragland PC, Nishimori RK, Greenberg JK, Hauck SA (1978) Varieties of granitic uranium deposits and favorable exploration areas in the eastern United States. Econ Geol 73:1539–1555

    Google Scholar 

  • Rosholt JN (1983) Isotopic composition of uranium and thorium in crystalline rocks. J Geophys Res 88:7315–7330

    Google Scholar 

  • Simmons G, Richter D (1976) Microcracks in rocks. In: RGJ Strens (ed) The Physics and Chemistry of Minerals and Rocks, Wiley-Interscience, New York pp 105–137

    Google Scholar 

  • Smedes HW (1980) Rationale for geologic isolation of high-level radioactive waste and assessment of the suitability of crystalline rock. USGS Open File Report 80-1065

  • Speer JA, Solberg TN, Becker SW (1981) Petrography of the uranium-bearing minerals of the Liberty Hill pluton, South Carolina: Phase assemblages and migration of uranium in granitoid rocks. Econ Geol 76:2162–2175

    Google Scholar 

  • Stuckless JS, Bunker CM, Bush CA, Doering WP, Scott JH (1977) Geochemical and petrological studies of a uraniferous granite from the Granite Mountains, Wyoming. J Res US Geol Survey 5:61–81

    Google Scholar 

  • Stuckless JS, Nkomo IT (1978) Uranium-lead isotope systematics in uraniferous alkali-rich granites from the Granite Mountains, Wyoming: Implications for uranium source rocks. Econ Geol 73:427–441

    Google Scholar 

  • Stuckless JS, Troeng B (1984) Uranium mineralization in response to regional metamorphism at Lilljuthatten, Sweden. Econ Geol 79:509–528

    Google Scholar 

  • Tieh TT, Ledger EB, Rowe MW (1980) Release of uranium from granitic rocks during in situ weathering and initial erosion (central Texas). Chem Geol 29:227–248

    Google Scholar 

  • Tieh TT, Ledger EB (1981) Fission track study of uranium in two granites of central Texas. Contrib Mineral Petrol 76:12–16

    Google Scholar 

  • Wollenberg HA, Smith AR (1968) Radiogeologic studies in the central part of the Sierra Nevada batholith. California, J Geophys Res 73:1481–1495

    Google Scholar 

  • Zielinski RA, Peterman ZE, Stuckless JS, Rosholt JN, Nkomo IT (1981) The chemical and isotopic record of rock-water interaction in the Sherman granite, Wyoming and Colorado. Contrib Mineral Petrol 78:209–219

    Google Scholar 

Download references

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  1. Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, 02139, Cambridge, Massachusetts

    Louis Caruso & Gene Simmons

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  1. Louis Caruso
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  2. Gene Simmons
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Caruso, L., Simmons, G. Uranium and microcracks in a 1,000-meter core, Redstone, New Hampshire. Contr. Mineral. and Petrol. 90, 1–17 (1985). https://doi.org/10.1007/BF00373036

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  • DOI: https://doi.org/10.1007/BF00373036

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