Skip to main content
Log in

Synthesis and properties of Mg-Zn-Al-SO4 hydrotalcite-like compounds

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Sulphate-based magnesium-zinc-aluminium synthetic hydrotalcite-like compounds have been prepared by coprecipitation with a sodium hydroxide solution. The corresponding metal solutions were coprecipitated at pH 10, aged in the mother liquor, washed several times and dried at 40 °C. Whatever the ratio of metal ions in the initial metal sulphate solutions, hydrotalcite compounds were formed during coprecipitation. The temperature of preparation and ageing time did not effect the final crystal structure. By comparing the properties of the Mg-Al layered compounds, it seems that when the zinc content increases, the thermal stability of the hydrotalcite-like compounds decreases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Allmann, Chimica 24 (1970) 99.

    CAS  Google Scholar 

  2. H. F. W. Taylor, Mineral. Mag. 37 (1969) 338.

    Article  CAS  Google Scholar 

  3. R. Allmann, Acta. Crystallogr. B24 (1968) 972.

    Article  Google Scholar 

  4. S. Miyata, Clays Clay Miner. 23 (1975) 369.

    Article  CAS  Google Scholar 

  5. M. C. Gastuche, G. Brown and M. M. Mortland, Clay Miner. 7 (1967) 177.

    Article  Google Scholar 

  6. S. Miyata and A. Okada, Clays Clay Miner. 25 (1977) 14.

    Article  Google Scholar 

  7. F. Thevenot, R. Szymanski and P. Chaumette, ibid. 37 (1989) 396.

    Article  CAS  Google Scholar 

  8. C. J. Serna, J. L. Rendon and J. E. Iglesias, ibid. 30 (1982) 180.

    Article  CAS  Google Scholar 

  9. B. J. Anderson and J. A. Whelan, Ged. Soc. Am., Special Paper 68 (1962) 83.

    Article  Google Scholar 

  10. S. Gusi, F. Trifiro, A. Vaccari and G. Del Piero, J. Catal. 94 (1985) 120.

    Article  CAS  Google Scholar 

  11. K. Hashi, S. Kikkawa and M. Koizumi, Clays Clay-Miner. 31 (1983) 152.

    Article  CAS  Google Scholar 

  12. M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon and C. J. Serna, Phys. Chem. Miner. 12 (1985) 34.

    CAS  Google Scholar 

  13. G. W. Brindley and S. Kikkawa, Amer. Mineral. 64 (1979) 836.

    CAS  Google Scholar 

  14. D. L. Bish, Bull. Miner. 103 (1980) 170.

    CAS  Google Scholar 

  15. G. W. Brindley and S. Kikkawa, Clays Clay Miner. 28 (1980) 87.

    Article  CAS  Google Scholar 

  16. P. G. Rouxhet and H. F. W. Taylor, Chimica 23 (1969) 480.

    CAS  Google Scholar 

  17. E. B. M. Doesburg, R. H. Höppener, B. De Koning, Xu. Xiao Ding and J. J. F. Scholten, in B. Delmon, P. Grange, P. A. Jacobs and G. Pancelet (editors), Preparation of Catalysts IV, (Elsevier, Amsterdam, 1987) p. 767.

    Google Scholar 

  18. V. P. Danilov, I. N. Lepeshkov, S. D. Litviniov, B. E. Yudovich, O. N. Krasnobaeva and L. T. Kotova, Russ. J. Inorg. Chem. 29 (1984) 982.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kooli, F., Kosuge, K., Hibino, T. et al. Synthesis and properties of Mg-Zn-Al-SO4 hydrotalcite-like compounds. JOURNAL OF MATERIALS SCIENCE 28, 2769–2773 (1993). https://doi.org/10.1007/BF00356216

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00356216

Keywords

Navigation